2,6-Dihydroxynaphthalene in the Synthesis of Naphthophosphacyclophanes

Phosphorylation of the 2,2'-Dihydroxy-1,1'-dinaphthylmethane and Synthesis of Phosphamacrocycles on its Basis

“…[1][2][3][4][5][6] As a result, there were synthesized macrocyclic compounds containing several fragments of macrocyclic diols and derivatives of phosphorous and phosphoric acids, which can be referred either as phosphacyclophanes or as benzocrown ethers. [7] Such compounds can be used in synthesis of polynuclear complexes with transition metals for catalytic purposes, as well as supramolecular receptors which can capture ions and small molecules, and for structural tasks of modern organoelemental chemistry.…”

Aminomethylated derivatives of 2,7-dihydroxynaphthalene

“…Therefore, the develop ment of available methods of synthesis of heterocyclic compounds and the study of their properties are rather topical tasks. The promising blocks for designing mac roheterocyclic compounds are dihydroxynaphtha lenes [1][2][3][4] containing both remote hydroxy groups and nitrogen containing substituents. The latter may be aminomethyl groups whose introduction into naphthalene derivatives is rather widely represented by aminomethylation reaction [5][6][7][8].…”