In graph theory, different types of matrices associated with graph, e.g. Adjacency matrix, Incidence matrix, Laplacian matrix etc. Among all adjacency matrix play an important role in graph theory. Many products of two graphs as well as its generalized form had been studied, e.g., cartesian product, 2−cartesian product, tensor product, 2−tensor product etc. In this paper, we discuss the adjacency matrix of two new product of graphs G H, where = ⊗2, ×2. Also, we obtain the spectrum of these products of graphs.