2-N,N-Dialkylamino-1,3-Dithiolium Salts

Abstract

The synthesis of 2-N,N-dialkylamino-1,3-dithiolium salts is reviewed.

4-(2-Hydroxyphenyl)-1,3-Dithiol-2-ylidene Derivatives

“…The main synthetic procedure for 1,3-dithiolium salts is represented by the acid catalyzed intramolecular cyclization of phenacyl carbodithioates [41][42][43][44][45][46]. A versatile synthesis of various salts of dithiocarbamic acid consists of reaction of secondary amine with carbon disulfide [68].…”

“…Moreover, novel dye-sensitized solar cells based on 1,3-dithiol-2-ylidene derivatives have been recently reported [33]. In general, charge-transfer [34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50] or pushpull [51-64] compounds have important applications in the field of conducting materials. An important precursor for 1,3-dithiol-2-ylidene derivatives are the 1,3-dithiolium-2-yl compounds [65,66].…”