1972
DOI: 10.1007/bf02609225
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2‐trans,4‐cis,7‐cis‐Decatrienal, the fishy off‐flavor occurring in strongly autoxidized oils containing linolenic acid or ω 3,6,9, etc., fatty acids

Abstract: A possible decomposition product of oils containing unsaturated fatty acids with the double bond pattern 603,6,9 or 603,6,9, etc., is 2-trans,4-cis, 7-cis-decatrienal. It has therefore been investigated whether this trienal is present in strongly autoxidized linolenic acid, soybean, linseed and fish oils. Via a degassing technique the carbonyls from the samples of oils heated in a closed system under nitrogen were collected and separated as their 2,4-dinitrophenylhydrazones (DNPHs) by thin layer chromatogra… Show more

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Cited by 76 publications
(32 citation statements)
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“…In source waters with minimal human impact, PUFA derivatives can produce brief and minor pulses of mild floral, fruity, or cucumberlike odors, which are usually undetected and/or removed by treatment. As human impacts increase, these peaks intensify in frequency and concentration, and generate unpleasant oily, pungent, rancid, or fishy odors (Meijboom & Stroink, 1972;Mallevialle & Suffet, 1987).…”
Section: Cucumber/floral/fishy/rancid/oily Odorsmentioning
confidence: 99%
See 1 more Smart Citation
“…In source waters with minimal human impact, PUFA derivatives can produce brief and minor pulses of mild floral, fruity, or cucumberlike odors, which are usually undetected and/or removed by treatment. As human impacts increase, these peaks intensify in frequency and concentration, and generate unpleasant oily, pungent, rancid, or fishy odors (Meijboom & Stroink, 1972;Mallevialle & Suffet, 1987).…”
Section: Cucumber/floral/fishy/rancid/oily Odorsmentioning
confidence: 99%
“…T/O can undergo abrupt or gradual seasonal changes in chemistry and biology. The odor of individual compounds varies with concentration or molecular isomers (Meijboom & Stroink, 1972). Mixes of volatile organic compounds (VOCs) or species can produce similar or different odors in source and finished water.…”
Section: T/o: the Consumer And The Drinking-water Industrymentioning
confidence: 99%
“…Primary products of this reaction are hydroperoxides and, in turn, these compounds lead to forming carbonyl compounds, such as ketones and aldehydes, alcohols and cyclic compounds. The typical secondary products of these hydroperoxides are 2,4,7-decatrienal isomers which introduce a fishy odor into oil at low concentrations (33). Products of this type of autoxidation are listed in Table V.…”
Section: Mechanism Of Lipid Autoxidation In Fish Oilsmentioning
confidence: 99%
“…3). While the primary hydroperoxides are without smell and taste, the secondary products give rise to the unpleasant sensory attributes of oxidised foods [52][53][54][55][56][57][58]. These volatiles also produce undesirable changes in colour.…”
Section: Composition and Oxidative Instability Of N-3 Fatty Acidsmentioning
confidence: 99%