2-(Methoxyimino)-2-{2-[(2-methylphenoxy)methyl]phenyl}acetohydrazide

Abstract

In the title mol­ecule, C17H19N3O3, the dihedral angle between the two benzene rings is 57.17 (5)°. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds connect mol­ecules to form chains along [001]. In addition, a weak C—H⋯π inter­action is observed.

5-([(Z)-Methoxyimino]{2-[(2-methylphenoxy)methyl]phenyl}methyl)-1,3,4-oxadiazole-2(3H)-thione dimethyl sulfoxide monosolvate

“…1) is derived from Kresoxim methyl fungicide and is a member of the strobilurin family. The broad spectrum nature of 1 allows it to have site-specific action and high efficacy against fungal diseases (Anke et al1977;Olaya et al 1998;Patel et al, 2012;Esteve-Turrillas et al, 2011;Mercader et al, 2008;Balba, 2007;Cash & Cronan, 2001, Ammermann et al, 2000Balba, 2007;Kant et al, 2012). The metabolites of compounds such as 1 are easily translocated in nature.…”

(Z)-N′-[(E)-4-Methoxybenzylidene]-2-(methoxyimino)-2-{2-[(2-methylphenoxy)methyl]phenyl}acetohydrazide

“…As these types of compounds are easily metabolized in nature as well as in living systems, their modifications are of importance in order to improve their activity (Balba, 2007). In order to increase the activity of the starting compounds (Kant et al 2012), it is necessary to modify the basic skeleton and initiate a structural investigation of different derivatives of kresoxim-methyl derivatives and in that light we previously reported the crystal structure of a related derivative, (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N 0 -(4-nitrobenzylidene)ethanohydrazide (Shripanavar & Butcher, 2015). This paper is a continuation in this series.…”

Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide

“…As these types of compounds are easily metabolized in nature as well as in living systems, their modifications are of immense importance (Balba, 2007). In order to increases the activity of starting compounds (Kant et al, 2012), it is necessary to modify their structures and to undertake a structural investigation of different kresoxim-methyl derivatives.…”