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Ko, An-Nan; Hung, Chiu-Yueh; Chen, Chih‐Wei; Ouyang, Kuang-Hao

doi:10.1023/a:1009038701442

Cited by 35 publications

(23 citation statements)

References 15 publications

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“…For the analysis of temperature-programmed desorption (TPD) of ammonia, the same apparatus as that of TPR was utilized. The procedures were described previously [7].…”

Section: Catalyst Characterizationmentioning

confidence: 99%

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Chin

Lin

2009

Catal Lett

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The vapour phase hydrogenation of cinnamaldehyde over Ni loading c-Al 2 O 3 catalysts was performed at 1 atm and 300°C in a fixed-bed reactor. The major product was hydrocinnamaldehyde. Unexpected products of styrene and ethylbenzene due to new reaction pathway of hydrodeformylation were observed. The results indicated that Ni metal was the active centers and the catalytic activity was parallel to the Ni surface area. The stability of TOF values implied that the cinnamaldehyde hydrogenation over Ni/cAl 2 O 3 catalysts was a structure insensitive reaction.

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“…For the analysis of temperature-programmed desorption (TPD) of ammonia, the same apparatus as that of TPR was utilized. The procedures were described previously [7].…”

Section: Catalyst Characterizationmentioning

confidence: 99%

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Chin

Lin

2009

Catal Lett

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“…The spectra for our samples (Al-M (20) and Al-M(60)), shown in Fig. 2, exhibit a peak at 59 ± 2 ppm corresponding to tetrahedral coordinated aluminum into the framework and a peak at 0 ± 2 ppm attributed to the octahedral coordinated extra framework aluminum [13][14][15][16]. The wt% of tetrahedral Al in the samples (Al Td wt%) was determined from the Al Td % (calculated from the integrated intensity of the NMR peak at 59 ± 2 ppm) multiplied with the overall Al content (Al wt%) (Table 1).…”

Section: Catalytic Reactionsmentioning

confidence: 90%

Selectively Obtaining ε-Caprolactam from Cyclohexanone Oxime Over Al-MCM-41 Catalysts

et al. 2013

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“…The procedures were described previously. 9 The catalyst reducibility was determined by monitoring the H 2 gas consumption through the temperature-programmed reduction (TPR) technique.…”

Section: Catalyst Characterizationmentioning

confidence: 99%

Liquid Phase Hydrogenation of t,t,c‐1,5,9‐Cyclododecatriene over Ni/MCM‐41 and Ni/SiO₂ Catalysts

Hsu

Wang

2009

J Chinese Chemical Soc

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Ni-loaded pure siliceous and aluminosilicate MCM-41 (Ni/MCM-41) and nickel-loaded silica (15Ni/ SiO 2 ) were synthesized via wet impregnation and were characterized by various techniques. The H 2 consumption in the TPR analysis was found to be proportional to the Ni amount in the calcined samples. After reduction the average Ni particle sizes of 15Ni/MCM-41 and 15Ni/SiO 2 were 9-12 and 16 nm, respectively, by means of XRD and TEM measurements. All catalysts owned weak and intermediate Lewis acid sites that increased slightly with increasing the Ni amount and the Al content. In the liquid phase hydrogenation of t,t,c-1,5,9-cyclododecatriene over Ni/MCM-41, the catalytic activity was parallel to the Ni content and enhanced slightly with the acid amount of the catalysts. Consequently, it was proposed that the Ni metallic sites contributed the major effect to the catalytic activity while the Lewis acid sites promoted a small but significant influence on the catalytic performance. It is noteworthy that all 15Ni/MCM-41 catalysts exhibited remarkably higher activity than that of the conventional 15Ni/SiO 2 catalyst.

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Cited by 35 publications

References 15 publications

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Selectively Obtaining ε-Caprolactam from Cyclohexanone Oxime Over Al-MCM-41 Catalysts

Liquid Phase Hydrogenation of t,t,c‐1,5,9‐Cyclododecatriene over Ni/MCM‐41 and Ni/SiO₂ Catalysts

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Untitled

Cited by 35 publications

References 15 publications

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Vapour Phase Hydrogenation of Cinnamaldehyde over Ni/γ-Al2O3 Catalysts: Interesting Reaction Network

Selectively Obtaining ε-Caprolactam from Cyclohexanone Oxime Over Al-MCM-41 Catalysts

Liquid Phase Hydrogenation of t,t,c‐1,5,9‐Cyclododecatriene over Ni/MCM‐41 and Ni/SiO2 Catalysts

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Liquid Phase Hydrogenation of t,t,c‐1,5,9‐Cyclododecatriene over Ni/MCM‐41 and Ni/SiO₂ Catalysts