25—The Reduction of the Aldehyde Groups in Periodate Oxycelluloses by Sodium Borohydride

“…Cuprammonium fluidity of exposed samples before and after sodium borohydride treatment, as suggested by Head [26], was determined with the help of burette viscometers standardized according to the specifications prescribe by A.S.T.M. [ 1 ] .…”

Section: Introductionmentioning

confidence: 99%

Photochemistry of Cotton and Chemically Modified Cotton

Daruwalla

D'Silva

Mehta

1967

Textile Research Journal

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A study has been made of photochemical degradation of cotton, mercerized cottons, partially acetylated cotton, and partially cyanoethylated cotton, during exposure to carbon-arc radiations under different conditions of atmosphere in the system and during exposure to selected wavelength bands in the visible and uv of sunlight. Exposed fiber substances have been examined for both mechanical and chemical damage suffered, and explanations have been put forth for the behavior of modified cottons on the basis of the nature of the modification effected through different treatments. ExperimentalMa.terials Californian cotton good Middling ( 1~ in. nominal staple and 4.3-4.4 micronair) was spun into 30s

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“…Cellulose oxidized to nearly stoichiometric levels with periodate dissolves in aqueous media during horohydride reduction [7]. Portions of the cellulose in resin-treated samples also dissolve as successive oxidations and reductions are carried out.…”

Section: Introductionmentioning

confidence: 99%

Chemical Structure of Resin-Treated Cellulose

Willard

Turner

Schwenker

1966

Textile Research Journal

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The chemical covalent bonding of trimethylolmelamine (TMM) with cotton cellulose produced under wet and dry curing conditions has been further investigated.The extent of chemical reaction with cellulose and the location of substituents on the anhydroglucose units were determined by an analytical scheme embodying chemical modification, complete hydrolysis, and gas chromatography of the analysis products. High temperature (160°C) curing gave rise to much greater extents of reaction with cellulose than curing under wet conditions. In the case of TMM, reaction at the primary. hydroxyl (C6) predominated at DS 0.16, whereas the major reaction of a methylated TMM having DS 0.30 occurred at C2. . ~ . I

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25—The Reduction of the Aldehyde Groups in Periodate Oxycelluloses by Sodium Borohydride

Cited by 39 publications

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Effect of Various Deacidification Solutions on the Stability of Cellulose Pulps

Effect of Various Deacidification Solutions on the Stability of Cellulose Pulps

Photochemistry of Cotton and Chemically Modified Cotton

Chemical Structure of Resin-Treated Cellulose

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