2017
DOI: 10.1038/s41598-017-05981-y
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2D/0D graphene hybrids for visible-blind flexible UV photodetectors

Abstract: Nitrogen-functionalized graphene quantum dots (NGQDs) are attractive building blocks for optoelectronic devices because of their exceptional tunable optical absorption and fluorescence properties. Here, we developed a high-performance flexible NGQD/graphene field-effect transistor (NGQD@GFET) hybrid ultraviolet (UV) photodetector, using dimethylamine-functionalized GQDs (NMe2-GQDs) with a large bandgap of ca. 3.3 eV. The NMe2-GQD@GFET photodetector exhibits high photoresponsivity and detectivity of ca. 1.5 × 1… Show more

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Cited by 43 publications
(34 citation statements)
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“…Tetsuka created a hybridized UV flexible photodetector based on these QDs (≈5 nm diameter) and a graphene monolayer. [93] The QDs hybridization with graphene helped to reduce the unintentional doping of graphene present in GFET, switching the Dirac point from 23.5 to 4.2 V. Furthermore, the architecture photoresponse was recordbreaking, reaching a responsivity of 1.5 × 10 4 A W −1 and detectivity of 5.5 × 10 11 . Comparing to previous architectures based in PbS QDs-Ag NCs that have only reached detectivity of 1.5 × 10 10 and a few mA W −1 of responsivity, [12] this architecture shows an improvement of more than one order of magnitude.…”
Section: Wwwadvmatinterfacesdementioning
confidence: 99%
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“…Tetsuka created a hybridized UV flexible photodetector based on these QDs (≈5 nm diameter) and a graphene monolayer. [93] The QDs hybridization with graphene helped to reduce the unintentional doping of graphene present in GFET, switching the Dirac point from 23.5 to 4.2 V. Furthermore, the architecture photoresponse was recordbreaking, reaching a responsivity of 1.5 × 10 4 A W −1 and detectivity of 5.5 × 10 11 . Comparing to previous architectures based in PbS QDs-Ag NCs that have only reached detectivity of 1.5 × 10 10 and a few mA W −1 of responsivity, [12] this architecture shows an improvement of more than one order of magnitude.…”
Section: Wwwadvmatinterfacesdementioning
confidence: 99%
“…Dimethylamine‐functionalized graphene QDs (NMe 2 ‐GQDs) show a large bandgap of 3.3 eV enabling UV photodetection with a cutoff frequency of ≈430 nm. Tetsuka created a hybridized UV flexible photodetector based on these QDs (≈5 nm diameter) and a graphene monolayer . The QDs hybridization with graphene helped to reduce the unintentional doping of graphene present in GFET, switching the Dirac point from 23.5 to 4.2 V. Furthermore, the architecture photoresponse was record‐breaking, reaching a responsivity of 1.5 × 10 4 A W −1 and detectivity of 5.5 × 10 11 .…”
Section: Progress Of 2d Materials Flexible Photodetectors Architecturesmentioning
confidence: 99%
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“…It has a good application prospect in the fields of LEDs, PDs, and flexible electronics. [133][134][135][136] In addition, the formation of heterogeneous structures and devices between QDs and other 1D or 2D materials is also one of the research hotspots 125,[137][138][139] ; for example, graphene/Cu 2 O QDs PDs. 140 In order to make the device with higher responsive, Cu 2 O QDs are introduced on the basis of graphene.…”
Section: D Materialsmentioning
confidence: 99%