It is also important for boiling flows [8,9] in a wide range of industrial applications.However, Bretherton's model did not take the surface wettability of the capillary wall into consideration. Except for Ratulowski and Chang [3], most of the analytical studies focused on the semi-infinite long bubble model, since Bretherton applied 'Lubrication Approximation' analysis on the trans ition region of a bubble. In this case, it is reasonable to assume a uniform interfacial liquid film under gas-liquid displacement when a plug bubble is moving along the capillary with a relatively large capillary number. However, it depends on the bubble velocity and the capillary's wettability. In this paper, low velocity bubbles with capillary numbers ranging from 0.001 to 0.01, (0.001 < Ca < 0.01) and bubble length range is L > 20 R (long bubble), will be investigated as shown in figure 1.To determine the liquid film thickness in experiments, Bretherton [1] and Schwartz et al [2] measured a plug of a wetting liquid moving along an initially dry glass capillary tube at constant velocity and calculated the liquid film thickness by Measurement Science and Technology