2D Metal-Free BSi<sub>5</sub> with an Intrinsic Metallicity and Remarkable HER Activity

Zhang, Wenyuan; Lou, Huan; Yang, Guochun

doi:10.1021/acs.jpclett.3c03055

Cited by 3 publications

(1 citation statement)

References 76 publications

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“…S, N-co-doped graphene typically exhibits superior performance compared to other co-doped combinations that yield inferior overpotentials and Tafel slopes. 219 2D BSi x compounds (x = 3−5) have delocalized π electrons and were calculated to have desirable HER properties with BSi 5 monolayer comparable to Pt. Its high HER activity was preserved at high H coverage and large biaxial strain.…”

Section: Metal-free Nanosheets and Hybrids For The Hermentioning

confidence: 99%

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Xu,

Iqbal,

Wang

et al. 2024

TIMS

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<p>Inorganic, organic, and hybrid two-dimensional (2D) materials are being developed for ever-expanding numbers of applications, though energy and catalysis remain the main drivers of their development. We present overviews of bottom-up and top-down synthetic strategies of such materials and examine manufacturing scalability issues. Mechanical, electrical, and thermal properties and their modulation are highlighted because they are fundamental to the above-mentioned drivers. The burgeoning importance of heterostructures in such materials, particularly for catalysis and electrode design and function is stressed. Detailed attention is given to applications of 2D materials to the electrocatalysis reactions: oxygen reduction, oxygen evolution, hydrogen evolution, carbon dioxide reduction, and nitrogen reduction. Water splitting, carbon dioxide reduction, and nitrogen reduction by photocatalysis are also examined. A perspective of expected advances in the expansion of applications and types of 2D materials, with a focus on heterostructure development, is presented in the conclusion.</p>

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Section: Metal-free Nanosheets and Hybrids For The Hermentioning

confidence: 99%

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Xu,

Iqbal,

Wang

et al. 2024

TIMS

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Effects of the coordination environment on the properties of the MnN2, MnCN, and MnC2 monolayers

Wang,

Yan,

Wang

et al. 2025

Applied Surface Science

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Metal-free borocarbonitrides as electrocatalysts for the hydrogen evolution reaction under alkaline media

Cencerrero,

Sánchez,

de Lucas-Consuegra

et al. 2025

Journal of Electroanalytical Chemistry

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2D Metal-Free BSi₅ with an Intrinsic Metallicity and Remarkable HER Activity

Cited by 3 publications

References 76 publications

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Effects of the coordination environment on the properties of the MnN2, MnCN, and MnC2 monolayers

Metal-free borocarbonitrides as electrocatalysts for the hydrogen evolution reaction under alkaline media

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2D Metal-Free BSi5 with an Intrinsic Metallicity and Remarkable HER Activity

Cited by 3 publications

References 76 publications

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Effects of the coordination environment on the properties of the MnN2, MnCN, and MnC2 monolayers

Metal-free borocarbonitrides as electrocatalysts for the hydrogen evolution reaction under alkaline media

Contact Info

Product

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About

2D Metal-Free BSi₅ with an Intrinsic Metallicity and Remarkable HER Activity