2022
DOI: 10.1039/d2qi00404f
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2D MOF nanosheets as an artificial light-harvesting system with enhanced photoelectric switching performance

Abstract: Herein, we report the synthesis, structure and photophysical properties of a novel well-defined layered metal-organic framework (MOF) [Cd(ppda)(mbib)] by the selection of two flexible ligands 1,4-phenylenediacetic acid (ppda) and 1,3-bis(imidazol-1-ylmethyl)benzene...

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Cited by 24 publications
(8 citation statements)
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“…The site-isolation of organometallics complexes in porous organic frameworks has emerged as a promising route to design artificial supramolecular assemblies for photocatalysis [1][2][3] . In these photoactive materials, the porous framework made of electron-rich organics linkers constitutes a large antenna [4][5][6][7][8][9][10] carrying out the absorptions of the photons and the subsequent conversion and transfer of the energy to the metal centres in charge of the catalytic activity.…”
Section: Introductionmentioning
confidence: 99%
“…The site-isolation of organometallics complexes in porous organic frameworks has emerged as a promising route to design artificial supramolecular assemblies for photocatalysis [1][2][3] . In these photoactive materials, the porous framework made of electron-rich organics linkers constitutes a large antenna [4][5][6][7][8][9][10] carrying out the absorptions of the photons and the subsequent conversion and transfer of the energy to the metal centres in charge of the catalytic activity.…”
Section: Introductionmentioning
confidence: 99%
“…In fact, as an emerging type of compound porous material, metal–organic frameworks (MOFs), composed of metal ions (clusters) and organic ligands by coordination bonds, have stimulated huge research interest in various optoelectronics fields due to their unique properties including tuned size, morphology, and porosity, especially the metal-porphyrinic frameworks , constructed with porphyrin as ligand (porphyrin MOFs) which has both MOFs and porphyrin molecular properties. Unfortunately, these powder or bulk MOF materials severely suffer from inherent deficiencies, including large scattering and difficult machining, hence not being suitable as optical devices.…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, this family of MOF magnets is composed of electrically neutral magnetic layers that are exclusively stacked by van der Waals interactions. This enables the possibility of mechanical exfoliation to a few layers [ 20 , 21 , 22 , 23 ], allowing the combination in an atomically-thin material the advantages of both MOFs and 2D magnetic crystals [ 24 , 25 ]. Furthermore, the fast development of on-surface synthetic approaches creates a promising route to achieve a scalable fabrication process [ 26 ], whereas long-range magnetic order and electronic communication between the spin carriers in the system can be favored by chemical substitution [ 27 , 28 ].…”
Section: Introductionmentioning
confidence: 99%