2D photosensitive porphyrin-based MOFs integrated with a Pd cocatalyst with fast charge transfer for efficient photocatalytic hydrogen evolution

Abstract

To improve the charge carriers transport efficiency via reducing the transmission distance, a series of 2D MOFs nanosheets with several transition metal clusters as metal nodes are prepared by a...

Photocatalytic ethene synthesis from ethane dehydrogenation with high selectivity by ZnO-supported Pt nanoparticles

“…4f). 59–61 The above outcomes authenticate that Pt/ZnO empowers improved separation and migration of photoinduced charge carriers, and therefore enabling the superior photocatalytic performance.…”

Metalation of metal–organic frameworks: fundamentals and applications

“…The electron-donating –SH group is able to coordinate with metal ions, especially precious metals. 117 2,5-dimercapto-1,4-benzenedicarboxylic acid (H 2 DMBD) is a representative ligand because the carboxylate backbone can form a coordination network as a linker, while peripheral mercaptan can be chelated with TM ions as active sites. He and co-workers reported a variant of H 2 DMBD, 1,4-dicarboxylbenzene-2,3-dithiol (H 2 dcbdt), whose two mercaptans are on the same side of the central phenyl.…”