3, 3’-sulfonyldipropionitrile: A novel additive to improve the high temperature performance of lithium-ion battery

Huang, Tao; Zheng, Xinwei; Pan, Ying; Wang, Wenguo; Gu, Fangna

doi:10.1016/j.electacta.2015.01.006

Cited by 19 publications

(5 citation statements)

References 22 publications

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“…Reproduced with permission. [94] Copyright 2015, Elsevier Ltd. SEI layer. The typical component LiF is insoluble in conventional electrolytes and has high Young's modulus and low electrical conductivity, which effectively inhibits the growth of lithium dendrites.…”

Section: Solventsmentioning

confidence: 99%

“…3,3'‐sulfonyl dipropionitrile (SDPN) is used as a film‐forming additive for LiMn 2 O 4 cathode at high temperatures, which is more easily oxidized than solvents and forms a thinner CEI layer on the cathode surface (Figure 8c–e). [ 94 ] With the electrolyte of 1.0 m LiPF 6 in EC/DMC/EMC (1:1:1 weight ratio) adding 0.5 wt.% SDPN, the capacity retention of Li||LiMn 2 O 4 batteries increased significantly from 56.7% (without additives) to 70.3% after 200 cycles at 55 °C. Leng et al.…”

Section: Progress Of Electrolytes For Lmbs At Elevated Temperaturesmentioning

confidence: 99%

“…Transmission electron microscopy images of c) pristine LiMn 2 O 4 electrode, and electrodes after 200 cycles at 55 °C in the electrolyte d) without and e) with 0.5 wt.% SDPN. Reproduced with permission [94]. Copyright 2015, Elsevier Ltd.…”

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confidence: 99%

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Research Progress of Liquid Electrolytes for Lithium Metal Batteries at High Temperatures

Nie,

Luo,

et al. 2023

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Lithium metal batteries (LMBs) are the most promising high energy density energy storage technologies for electric vehicles, military, and aerospace applications. LMBs require further improvement to operate efficiently when chronically or routinely exposed to high temperatures. Electrolyte engineering with high temperature tolerance and electrode compatibility has been essential to the development of LMBs. In this review, the primary obstacles to achieving high‐temperature LMBs are first explored. Subsequently, electrolyte tailoring options, such as lithium salt optimization, solvation structure modification, and the addition of additives are reviewed in detail. In addition, the feasibility of utilizing LMBs at high temperatures has been investigated. In conclusion, this study provides insights and perspectives for future research on electrolyte design at high temperatures.

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Section: Solventsmentioning

confidence: 99%

Section: Progress Of Electrolytes For Lmbs At Elevated Temperaturesmentioning

confidence: 99%

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Research Progress of Liquid Electrolytes for Lithium Metal Batteries at High Temperatures

Nie,

Luo,

et al. 2023

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“…此外, SDPN (70, 图 13)可优先氧化形成 CEI 膜, 在 4.6 V 及 55 ℃时具有优良的性能 [170,171] . 类似的还有 DMSM、DPDS 及 DVS (71～73, 图 13)等 [172～174] .…”

Section: 其它含硫添加剂unclassified

Review of Electrolyte Additives for Ternary Cathode Lithium-ion Battery

Deng¹,

Sun²,

Wan³

et al. 2018

Acta Chim. Sinica

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, M＝Mn, NMC; M＝Al, NCA)} are one of the most promising cathode materials of lithium-ion batteries (LIBs). However, in the traditional electrolyte system, they will undergo dramatic structural changes and interface side reactions at high potential and high temperature, which will bring great challenges to their practical application, especially for their cycle life and safety. Developing appropriate electrolyte additive is one of the most economical and effective methods to improve the electrochemical performance of LIBs. Based on the intrinsic structure of material, electrolyte additives used for NMC and NCA ternary cathode and their reaction mechanism in the past 5 years are reviewed in this paper, which include vinylene carbonate (VC), fluoro-compounds, new lithium salts, P-based, B-based, S-based, nitrile, others and combinative additives. Among them, VC becomes a kind of universal additive, which can improve the efficiency and cycle life at low voltage and normal temperature. Fluoro-compounds have been developed from mono substituted such as Fluorinated ethylene carbonate (FEC) to multi-fluorine substituted, which can improve the stability of electrode/electrolyte interface under high voltage. New lithium salt additives are mainly used to improve the film forming performance under high voltage and high temperature, such as Lithium bis(fluorosulfonyl)imide (LiFSI), Lithium difluorophosphate (LiDFP). P-contained additives [such as Tris(trimethylsilyl)phosphite (TMSPi)] are mainly to improve the stability of anode-electrolyte interface, and it has obvious synergistic effect when they combined with additives such as VC. B-contained additives are mainly used to improve the dissociation degree and stability of lithium salt, such as Tris(trimethylsilyl)borate (TMSB). S-contained additives are mainly used to improve the ionic conductivity and stability of anode SEI film, such as Prop-1-ene-1,3-sultone (PES). Nitriles are benefited from the strong electron withdrawing effect of -CN, which can improve the stability of the electrode/electrolyte interface at high voltage. Other types of additives are some heterocyclic compounds having film forming ability and various silanes which can eliminate HF and H 2 O. Combinative additives are developed from VC based composite to PES and PBF (pyridine boron trifluoride) system, which can endure even harsher conditions.

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“…Various SEI-film forming additives have been used for enhancing the high temperature stability of the LiMn 2 O 4 -based cells, including sulfur-containing compounds such as methylene methanedisulfonate (Zuo et al, 2014), prop-1-ene-1, 3-sultone , P-toluenesulfonyl isocyanate (Wang et al, 2015), 3, 3 -sulfonyldipropionitrile (Huang et al, 2015), and butyl sultone (Xu et al, 2007). The sulfur-containing substances generated from the additives decomposition can deactivate many catalysts (Czekaj et al, 2011).…”

Section: Introductionmentioning

confidence: 99%

Improving Cyclic Stability of LiMn2O4/Graphite Battery Under Elevated Temperature by Using 1, 3-Propane Sultone as Electrolyte Additive

Liu

et al. 2020

Front. Mater.

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Spinel lithium manganese oxide (LiMn 2 O 4) based Li-ion battery (LIB) is attractive for hybrid/full electric vehicles because of its abundant resources and easy preparation. However, operation under an elevated temperature could cause severe capacity fading of the spinel cathodes. In this work, 1, 3-propane sultone (PS) is investigated as an electrolyte additive for improving the cyclability of the LiMn 2 O 4 /graphite LIB at elevated temperature. The charge and discharge measurement proves that PS can significantly enhance the cyclability of 053048-type LiMn 2 O 4 /graphite pouch cell at 60 • C. Compared to the cell without additive, the capacity retention of the cell using electrolyte with 5% PS increases from 52 to 71% after 180 cycles. The improved cyclability is attributable to the modification of the solid electrolyte interface (SEI) on both positive and negative sides of the LiMn 2 O 4 /graphite cell by PS, which effectively prevents anode and cathode from structural breakdown and inhibits the electrolyte decomposition.

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3, 3’-sulfonyldipropionitrile: A novel additive to improve the high temperature performance of lithium-ion battery

Cited by 19 publications

References 22 publications

Research Progress of Liquid Electrolytes for Lithium Metal Batteries at High Temperatures

Research Progress of Liquid Electrolytes for Lithium Metal Batteries at High Temperatures

Review of Electrolyte Additives for Ternary Cathode Lithium-ion Battery

Improving Cyclic Stability of LiMn2O4/Graphite Battery Under Elevated Temperature by Using 1, 3-Propane Sultone as Electrolyte Additive

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