3,5‐Diaza‐1‐Azonia‐7‐Phosphatricyclo[3.3.1.1
            <sup>3,7</sup>
            ]decane, 1‐(4‐Sulfobutyl)‐, Inner Salt

Kapdi, Anant R.; Bhilare, Shatrughn; Shah, Jagrut A.; Parmar, Udaysinh

doi:10.1002/047084289x.rn02316.pub2

Encyclopedia of Reagents for Organic Synthesis 2021

DOI: 10.1002/047084289x.rn02316.pub2

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3,5‐Diaza‐1‐Azonia‐7‐Phosphatricyclo[3.3.1.1 ^3,7 ]decane, 1‐(4‐Sulfobutyl)‐, Inner Salt

Anant R. Kapdi

Shatrughn Bhilare

Jagrut A. Shah

et al.

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2024

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Cited by 2 publications

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Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Patel,

Kapdi

2024

The Chemical Record

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Catalysis has been at the forefront of the developments that has revolutionised synthesis and provided the impetus in the discovery of platform technologies for efficient C−C or C−X bond formation. Current environmental situation however, demands a change in strategy with catalysis being promoted more in solvents that are benign (Water) and for that the development of hydrophilic ligands (especially phosphines) is a necessity which could promote catalytic reactions in water, allow recyclability of the catalytic solutions and make it possible to isolate products using column‐free techniques that involve lesser usage of hazardous organic solvents. In this review, we therefore critically analyse such catalytic processes providing examples that do follow the above‐mentioned parameter.

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Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Patel,

Kapdi

2024

The Chemical Record

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Discovery, Synthesis, and Scale-up of Efficient Palladium Catalysts Useful for the Modification of Nucleosides and Heteroarenes

Bhilare

Shet

Sanghvi³

et al. 2020

Molecules

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Nucleic acid derivatives are imperative biomolecules and are involved in life governing processes. The chemical modification of nucleic acid is a fascinating area for researchers due to the potential activity exhibited as antiviral and antitumor agents. In addition, these molecules are also of interest toward conducting useful biochemical, pharmaceutical, and mutagenic study. For accessing such synthetically useful structures and features, transition-metal catalyzed processes have been proven over the years to be an excellent tool for carrying out the various transformations with ease and under mild reaction conditions. Amidst various transition-metal catalyzed processes available for nucleoside modification, Pd-catalyzed cross-coupling reactions have proven to be perhaps the most efficient, successful, and broadly applicable reactions in both academia and industry. Pd-catalyzed C–C and C–heteroatom bond forming reactions have been widely used for the modification of the heterocyclic moiety in the nucleosides, although a single catalyst system that could address all the different requirements for nucleoside modifications isvery rare or non-existent. With this in mind, we present herein a review showcasing the recent developments and improvements from our research groups toward the development of Pd-catalyzed strategies including drug synthesis using a single efficient catalyst system for the modification of nucleosides and other heterocycles. The review also highlights the improvement in conditions or the yield of various bio-active nucleosides or commercial drugs possessing the nucleoside structural core. Scale ups wherever performed (up to 100 g) of molecules of commercial importance have also been disclosed.

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3,5‐Diaza‐1‐Azonia‐7‐Phosphatricyclo[3.3.1.1 ^3,7 ]decane, 1‐(4‐Sulfobutyl)‐, Inner Salt

Cited by 2 publications

References 44 publications

Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Discovery, Synthesis, and Scale-up of Efficient Palladium Catalysts Useful for the Modification of Nucleosides and Heteroarenes

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Product

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About

3,5‐Diaza‐1‐Azonia‐7‐Phosphatricyclo[3.3.1.1 3,7 ]decane, 1‐(4‐Sulfobutyl)‐, Inner Salt

Cited by 2 publications

References 44 publications

Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Ubiquitous Role of Phosphine‐Based Water‐Soluble Ligand in Promoting Catalytic Reactions in Water

Discovery, Synthesis, and Scale-up of Efficient Palladium Catalysts Useful for the Modification of Nucleosides and Heteroarenes

Contact Info

Product

Resources

About

3,5‐Diaza‐1‐Azonia‐7‐Phosphatricyclo[3.3.1.1 ^3,7 ]decane, 1‐(4‐Sulfobutyl)‐, Inner Salt