3-(Ammoniomethyl)pyridinium bis(perchlorate)

Abstract

In the title molecular salt, C6H10N2 2+·2ClO4 −, the Cl—O bond lengths [anion 1: 1.369 (3)–1.415 (3); anion 2: 1.420 (2)–1.441 (2) Å] and the O—Cl—O angles [anion 1: 105.4 (2)–111.8 (4); anion 2: 107.8 (1)–110.3 (1)°] indicate a slight distortion of the perchlorate anions from regular tetra­hedral symmetry. In the crystal, the components are linked into columns along the a-axis direction via N—H⋯O and C—H⋯O hydrogen bonds, with stacks of the organic mol­ecules being surrounded by stacks of perchlorate anions.

Synthesis, Crystal Structure, Hirshfeld Surface, and Physicochemical Characterization of New Salt Bis(2-ethyl-6-methylanilinium)tetrachloromercurate (II) [C9H14N]2HgCl4

“…e synergy between the electrical, thermal, and optical properties of inorganic entities and the physicochemical properties of organic materials opens up a vast field of their applications. ese materials, made by combining different components, aim to produce desirable properties and functionalities and at the same time reduce or eliminate undesirable effects [1][2][3][4][5][6][7][8].…”