The title compound, C9H3F5O2, crystallizes as O—H⋯O hydrogen-bonded carboxylic acid dimers that, together with C—H⋯F interactions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via short π–π interactions [centroid–centroid distance = 4.3198 (11) Å]. An intramolecular C—H⋯F interaction is also observed.