3-Methoxy-N-[2-(methylsulfanyl)phenyl]salicylaldimine

Abstract

Key indicatorsSingle-crystal X-ray study T = 100 K Mean (C-C) = 0.002 Å R factor = 0.030 wR factor = 0.079 Data-to-parameter ratio = 22.2 For details of how these key indicators were automatically derived from the article, see

N-(3,5-Dimethoxybenzylidene)-2-(methylsulfanyl)aniline

“…deviation of 0.0253Å . The C N double-bond length is 1.2744 (19)Å , in agreement with values in related molecules (Hamaker & Corgliano, 2006;.…”

N-[2-(Benzylsulfanyl)benzylidene]-2-(methylsulfanyl)aniline

“…The C2-C7 arene ring is twisted away from coplanarity to relieve the steric repulsion between H12 and the SCH 3 group, with a C10-N-C7-C2 torsion angle of 140.7 (2) . The N C10 double-bond length is 1.274 (3) Å , similar to that in related molecules (Hamaker & Corgliano, 2006;Ainscough et al, 2000;Ö zbey et al, 1998).…”

“…Schiff base ligands are also readily modified, both sterically and electronically. Our group is interested in the synthesis and utility of sulfur-containing Schiff base ligands (Hamaker & Halbach, 2006;Hamaker & Corgliano, 2006). As part of our ongoing studies, we report the synthesis and crystal structure of the title compound, (I).…”

3,5-Di-tert-butyl-N-[2-(methylsulfanyl)phenyl]salicylaldimine

“…1), with a dihedral angle between the two aromatic rings of 32.06 (9) . The bond lengths and angles (Table 1) are similar to those of related molecules (Hamaker & Corgliano, 2006;. Similar to the 3-methoxy derivative, there is an intramolecular O1-H1Á Á ÁN1 hydrogen bond (Table 2).…”

“…Unlike the 3-methoxy derivative (Hamaker & Corgliano, 2006), the molecule of (I) is non-planar ( Fig. 1), with a dihedral angle between the two aromatic rings of 32.06 (9) .…”