3-Phenyl-4-benzoyl-5-isoxazolone: A promising chelate extractant for actinide separation from acidic nuclear waste solutions

Manchanda, V. Κ.; Mohapatra, P. Κ.; Veeraraghavan, R.

doi:10.1016/0003-2670(95)00607-9

Analytica Chimica Acta

1996

DOI: 10.1016/0003-2670(95)00607-9

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3-Phenyl-4-benzoyl-5-isoxazolone: A promising chelate extractant for actinide separation from acidic nuclear waste solutions

V. Κ. Manchanda¹,

P. Κ. Mohapatra²,

R. Veeraraghavan³

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Cited by 18 publications

References 7 publications

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Synergistic Extraction of Cobalt (II) by β Hydroxy Naphthaldoxime and Neutral Donors

Banerjee¹,

Basu²

2004

Annali di Chimica

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Liquid - liquid extraction of Cobalt (II) from aqueous hydrochloric acid medium by the use of oxime derivative of beta-hydroxy naphthaldehyde in o-xylene medium is being reported. The ligand was synthesized and characterized in our laboratory. The typical pH range of extraction of Co (II) by the ligand - donor combination was seen to be between 8 - 9. The effect of different donors like dimethyl sulphoxide (DMSO), trioctyl phosphine oxide (TOPO) and bis(2-ethylhexyl) phosphonate and the effect of various diluents on the extraction of Co(II) by the present method were studied in detail. The binary adduct formation constant (log kex) in the organic phase was found to be 3.182. The overall equilibrium constant (log K) for the ternary species [Co(A)(DMSO)(Cl)], [Co(A)(TOPO)(Cl)] and [Co(A)(phosphonate)(Cl)] were estimated to be 6.42, 6.22 and 6.25 respectively. The trend in equilibrium constants were in accordance with their basic character, i.e., (DMSO > or = TOPO approximately/= phosphonate). The results were extrapolated in the determination of Cobalt in pharmaceutical drugs and cobalt bearing ore samples.

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Synergistic Extraction of Cobalt (II) by β Hydroxy Naphthaldoxime and Neutral Donors

Banerjee¹,

Basu²

2004

Annali di Chimica

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Distribution behavior of U(VI), Am(III) and Eu(III) on diglycolamide based extraction chromatographic resin in perchloric acid medium

Vyas

Joshirao

Bagla³

et al. 2013

J Radioanal Nucl Chem

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Acylisoxazolone-impregnated Si-MCM-41 mesoporous materials as promising liquid–solid extractants of metals

Miloudi

Boos

Bouazza

et al. 2007

Materials Research Bulletin

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3-Phenyl-4-benzoyl-5-isoxazolone: A promising chelate extractant for actinide separation from acidic nuclear waste solutions

Cited by 18 publications

References 7 publications

Synergistic Extraction of Cobalt (II) by β Hydroxy Naphthaldoxime and Neutral Donors

Synergistic Extraction of Cobalt (II) by β Hydroxy Naphthaldoxime and Neutral Donors

Distribution behavior of U(VI), Am(III) and Eu(III) on diglycolamide based extraction chromatographic resin in perchloric acid medium

Acylisoxazolone-impregnated Si-MCM-41 mesoporous materials as promising liquid–solid extractants of metals

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