Hyperfluorescence has received significant attention as a promising strategy to design organic light-emitting diodes (OLEDs) with high color purity and enhanced stability. In this approach, emitters displaying strong and narrowband fluorescence are integrated in thin films that contain sensitizers showing efficient thermally activated delayed fluorescence (TADF). To ensure high performance, the energies of the electronic states in the fluorescent emitters must be well-aligned, with respect to those in the TADF molecules, in order to enable a fast rate of Forster singlet-exciton energy transfer from the latter to the former. Here, we performed molecular dynamics simulations and density functional theory calculations to study a series of fluorescent emitters commonly considered in hyperfluorescence OLEDs. For all these emitters, the lowest triplet excited state (T 1 FE ) is found to locate substantially below the lowest singlet excited state (S 1 FE