333. Acid catalysis in non-aqueous solvents. Part III. The rearrangement of N-iodoformanilide in anisole solution

The Orton rearrangement in aprotic solvents. Part IV. An examination of the kinetics of the rearrangement of N-bromo-4-chloroacetanilide and N-bromoacetanilide catalyzed by trifluoroacetic acid and trifluoroacetic acid-d

“…Hence, both the magnitude and reproduciview of these comparisons, the Kd values deter-bility of the Kd values lend some credence to the mined here appear to be of the correct order of approximations implicit in the rate law of eq. [17] magnitude.…”

“…In view of this result, eq. [17] is clearly the simplest rate law which can accommodate concentration dependent maxima in the a versus c, plots for the NBCAITFA, NBCAITFA-d, and NBAITFA systems (see Fig. 2).…”

“…[19] with respect to c,leads to the conclusion that the rate law given by eq. [17], when taken in conjunction with the concentration expression of eq. [5], will yield a maximum in the a ,c, coordinate system.…”

“…[17] using the method suggested by Wentworth (24) for nonlinear regression. The regression results, quoted in Table 5 Table 5 should reflect primarily on the validity of the data treatment and ultimately on the justification for the assumption which constrains catalytic reactivity to the monomeric species in the simple monomer-dimer acid equilibrium.…”