Characterization
of microscopic structure and macroscopic physical
property are the basis for better understanding of coalbed methane
reservoirs. X-ray computed tomography (CT), as an nondestructive measurement,
has been widely and successfully applied to characterize the internal
structure of coal. In this study, we introduce the principle of CT
imaging and the microstructure recognition. A summary of CT imaging-based
coal microstructure characterization follows, including three-dimensional
(3D) microstructure reconstruction, pore and mineral quantification,
and equivalent pore network model construction. We review the methods
used to evaluate the macroscopic properties of coal, including porosity
calculation, gas adsorption/diffusion rate test, permeability simulation,
and mechanical behavior evaluation. This study discusses the application
of CT to investigate the evolutionary mechanisms of microstructure
and macroscopic properties during gas adsorption, temperature change,
and damage deformation. We conclude this review with a summary of
the challenges and application perspectives of CT. The small scanning
range, limited observation accuracy, functional limitations, lengthy
testing process, and high cost are some of the major hurdles in the
broad application of CT for coal characterization. In the future,
CT should be combined with other techniques to establish full-scale
pore and fracture models, identify mineral types in microstructures,
and effusively use the advantages of CT by selecting the key points
in the evolutionary mechanisms of microstructure and macroscopic properties.