This paper presents a robust intelligent tracking-control technique which is subsequently applied to single-phase SPWM inverters. The proposed technique mixes advanced sliding mode control (ASMC) with grey-Markov model (GMM). The advanced sliding mode control allows the system state to converge quickly to the origin in a limited amount of time. Unfortunately, a chattering problem frequently occurs when the inverter suffers drastically from highly nonlinear or internal parameters changes. The large power losses and high harmonic distortion emerge in the inverter output. The role that the grey-Markov model plays is to reduce the chattering of the ASMC during system uncertainty overestimation, or to reduce the steady-state error caused by underestimation of system uncertainty. In conjunction with the GMM and the ASMC, fast transient response, low distortion of the sinusoidal output-voltage and reduced chattering can be obtained. Simulation results of the proposed single-phase SPWM inverter are carried out in MATLAB/Simulink. The experimental results have been validated through digital signal processors, enabling the single-phase SPWM inverter output to effectively improve the transient tracking speed and steady-state performance.