3D Nanocellulose Matrix Enhancing the Lithiation Dynamics of FePS<sub>3</sub> Anode

Xiao, Zhe; Dai, Xiangyu; Jiang, Dongting; Xie, Honggui; Liu, Xueping; Wang, Mingli; Liu, Dongming; Li, Yi; Qian, Zhengfang; Wang, Renheng

doi:10.1002/adfm.202304766

Cited by 12 publications

(1 citation statement)

References 48 publications

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“…The innate and superior chemical functionality endows biomass with substantial potential for synthesizing various morphological and functional architectures. Notably, employing specific methods, such as carbonization [12], electrostatic spinning [13], and vacuum filtration [14], facilitates the production of flexible carbon membranes/monolithic free-standing materials, which are distinguished by their large specific surface area, abundant functional groups, and three-dimensional (3D) mesh structure. Moreover, exceptional folding and bending capabilities, coupled with excellent electrical conductivity, render these materials highly promising for utilization as flexible electrode materials in energy storage devices, encompassing metal-ion batteries [15], supercapacitors [16], and metal-air batteries [17], thus ideally fulfilling the requirements of next-generation flexible electronic devices.…”

Section: Introductionmentioning

confidence: 99%

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Yang,

Xu,

Tian

et al. 2023

Molecules

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With the swift advancement of the wearable electronic devices industry, the energy storage components of these devices must possess the capability to maintain stable mechanical and chemical properties after undergoing multiple bending or tensile deformations. This circumstance has expedited research efforts toward novel electrode materials for flexible energy storage devices. Nonetheless, among the numerous materials investigated to date, the incorporation of metal current collectors or insulative adhesives remains requisite, which entails additional costs, unnecessary weight, and high contact resistance. At present, biomass-derived flexible architectures stand out as a promising choice in electrochemical energy device applications. Flexible self-supporting properties impart a heightened mechanical performance, obviating the need for additional binders and lowering the contact resistance. Renewable, earth-abundant biomass endows these materials with cost-effectiveness, diversity, and modulable chemical properties. To fully exploit the application potential in biomass-derived flexible carbon architectures, understanding the latest advancements and the comprehensive foundation behind their synthesis assumes significance. This review delves into the comprehensive analysis of biomass feedstocks and methods employed in the synthesis of flexible self-supporting carbon electrodes. Subsequently, the advancements in their application in energy storage devices are elucidated. Finally, an outlook on the potential of flexible carbon architectures and the challenges they face is provided.

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Section: Introductionmentioning

confidence: 99%

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Yang,

Xu,

Tian

et al. 2023

Molecules

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Vacancy‐Rich Ternary Iron Phosphoselenide Multicavity Nanorods: A Highly Reversible and Fast Anode for Sodium‐Ion Batteries

Tian,

Sun,

et al. 2024

Adv Funct Materials

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The significance of exploring optimal electrode materials cannot be overstated, particularly in mitigating the critical issues posed by sluggish redox kinetics, significant volume variations, and severe structural collapse resulting from the insertion and extraction of sodium ions. These efforts are crucial for enhancing the longevity and rapid charging capabilities of sodium‐ion batteries (SIBs). Herein, a defect engineering strategy for the in situ encapsulation of single‐phase ternary iron phosphoselenide into porous carbon by robust chemical bonds with the formation of rod‐like multicavity nanohybrids (FePSe3@C) is presented. The incorporation of Se atom not only modulates the electronic structure of the central metal Fe atom and enhances the intrinsic electrical conductivity, but also generates numerous additional reaction sites and accelerates the reaction kinetics of FePSe3@C, as corroborated by theoretical calculations and kinetic analysis. Notably, the FePSe3@C demonstrates an outstanding rate capability of 321.7 mAh g−1 even at 20 A g−1 and long cycling stability over 1000 cycles. The sodium‐ion full cell, pairing the FePSe3@C anode with the Na3V2(PO4)3@C cathode, exhibits a remarkable energy density of 202 Wh kg−1, demonstrating its practical applicability. This work provides a controllable defect and morphology engineering strategy to construct advanced materials with fast charge transfer for high‐power/energy SIBs.

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2D Metal Phosphorous Trichalcogenides (MPCh₃) for Sustainable Energy Storage and Conversion: Nanoarchitectonics and Advanced Applications

Wang,

Cheng,

et al. 2024

Adv Funct Materials

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Abstract2D metal phosphorous trichalcogenides (MPCh3) have attracted considerable attention in sustainable energy storage and conversion due to their distinct physical and chemical characteristics, such as adjustable energy bandgap, significant specific surface area, and abundant active sites. However, research on 2D MPCh3 primarily focuses on electrocatalysis, and understanding its energy conversion and storage mechanisms remains incomplete. This review comprehensively summarizes recent advancements in energy storage and conversion using 2D MPCh3‐based materials of various structures. It begins with a discussion of the distinctive properties and preparation techniques of 2D MPCh3, followed by a focus on the rational design and development of these materials for diverse energy‐related applications, including rechargeable batteries, supercapacitors, electrocatalysis, photocatalysis, and desalination. Finally, it outlines the key challenges and prospects for future research on 2D MPCh3 materials.

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3D Nanocellulose Matrix Enhancing the Lithiation Dynamics of FePS₃ Anode

Cited by 12 publications

References 48 publications

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Vacancy‐Rich Ternary Iron Phosphoselenide Multicavity Nanorods: A Highly Reversible and Fast Anode for Sodium‐Ion Batteries

2D Metal Phosphorous Trichalcogenides (MPCh₃) for Sustainable Energy Storage and Conversion: Nanoarchitectonics and Advanced Applications

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3D Nanocellulose Matrix Enhancing the Lithiation Dynamics of FePS3 Anode

Cited by 12 publications

References 48 publications

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Biomass-Derived Flexible Carbon Architectures as Self-Supporting Electrodes for Energy Storage

Vacancy‐Rich Ternary Iron Phosphoselenide Multicavity Nanorods: A Highly Reversible and Fast Anode for Sodium‐Ion Batteries

2D Metal Phosphorous Trichalcogenides (MPCh3) for Sustainable Energy Storage and Conversion: Nanoarchitectonics and Advanced Applications

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Product

Resources

About

3D Nanocellulose Matrix Enhancing the Lithiation Dynamics of FePS₃ Anode

2D Metal Phosphorous Trichalcogenides (MPCh₃) for Sustainable Energy Storage and Conversion: Nanoarchitectonics and Advanced Applications