2017
DOI: 10.1039/c7mh00072c
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3D printable light-responsive polymers

Abstract: New photo-curable polymers suitable for 3D printing are here provided, exhibiting a mechanical light-responsivity upon laser irradiation. Azobenzene moieties are employed both as a dye component in the 3DP and as active groups, providing photo-mechanical responsivity. The incorporation of azobenzene units into polymeric matrices allows a reversible and controllable change of the Young's modulus of 3D printed micrometric structures.

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Cited by 101 publications
(82 citation statements)
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“…This separation between indents was imposed to avoid the influence of neighbour indentations. The maximum applied load was of 100 N. The average Young's modulus (E) and H measured values were 3.070±0.010 MPa, and 744.21±5.40 kPa respectively, which are in accordance with previous studies [13]. The mechanical response of the 3D-printed polymer is shown in Fig.…”
Section: A Mechanical Propertiessupporting
confidence: 74%
“…This separation between indents was imposed to avoid the influence of neighbour indentations. The maximum applied load was of 100 N. The average Young's modulus (E) and H measured values were 3.070±0.010 MPa, and 744.21±5.40 kPa respectively, which are in accordance with previous studies [13]. The mechanical response of the 3D-printed polymer is shown in Fig.…”
Section: A Mechanical Propertiessupporting
confidence: 74%
“…We utilize Polyjet photopolymer technology that allows multi-material deposition [29][30][31][32] to 3D print compliance-tailored single-lap joints (SLJs), as shown in Figure 1a (top). The emergence of such multi-material and composite 3D printing technologies [33][34][35][36][37][38][39] facilitates the design of functionally graded designs at the sub-millimeter scale enabling fabrication of multi-material structures simultaneously exhibiting both strength and toughness, which are often difficult to achieve with homogeneous materials.…”
Section: D Printing and Compliance-tailoring Of The Multimaterials Jointmentioning
confidence: 99%
“…Formulations III and IV were used in ad igital light processing (DLP) [17] 3D printer with LEDs (405 nm) for 3D printing. In spite of the high swellability,s hape-persistent, free-standing 3D structured objects can be printed.…”
Section: Zuschriftenmentioning
confidence: 99%