In the automotive, aerospace, and defense industries, there is a need for additively manufactured components that are capable of multiple functions or enhanced performance, but can also withstand extreme environments. Existing material sets for additively manufactured components are generally unsuitable for extreme environments, which limit their practical use. Both top-down and bottom-up approaches for innovation can guide the development of new materials and processes that address the shortcomings of the existing material sets. This manuscript will discuss the development of new composite materials and processing using direct ink writing additive manufacturing for use in functional and environmental extremes. To demonstrate how these materials and methods outperform those in existence, three vignettes will be highlighted. Due to the simplicity of our approaches and the consequential implications of their use, we expect the wide adoption of these materials and methods. In addition to the increased acceptance of additively manufactured components for practical applications, especially those in extreme environments, there is also the potential for more far-reaching technological advantages.