4,4′-Bis(2,6-dichlorobenzylideneamino)biphenyl

The title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for molecules A and B, respectively. In the crystal, A molecules are related as centrosymmetric pairs through a weak π–π interaction [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of intermolecular C—H⋯O, C—H⋯N and C—H⋯π interactions present.

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N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine

Subashini

Ramamurthi

Stœckli-Evans

2011

Acta Cryst E

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4,4′-Bis(2,6-dichlorobenzylideneamino)biphenyl

Abstract: Key indicatorsSingle-crystal X-ray study T = 291 K Mean (C-C) = 0.003 Å Disorder in main residue R factor = 0.052 wR factor = 0.167 Data-to-parameter ratio = 11.5For details of how these key indicators were automatically derived from the article, see

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N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine

N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine

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