4,5-Diiodo-1-<i>H</i>-imidazole-derived linker ligand and Cu(<scp>i</scp>) and Co(<scp>ii</scp>) coordination polymers based thereupon

Zaguzin, Alexander S.; Zaitsev, Artem V.; Korobeynikov, Nikita A.; Novikov, Alexander S.; Usoltsev, Andrey N.; Fedin, Vladimir P.; Adonin, Sergey A.

doi:10.1039/d4ce00072b

CrystEngComm

2024

DOI: 10.1039/d4ce00072b

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4,5-Diiodo-1-H-imidazole-derived linker ligand and Cu(i) and Co(ii) coordination polymers based thereupon

Alexander S. Zaguzin,

Artem V. Zaitsev,

Nikita A. Korobeynikov

et al.

Abstract: The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...

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Cited by 2 publications

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Synthesis, characterization and study of magnetic property of two isomorphic Cu(II) coordination polymers (CP) with chromone based ligand systems

Mandal,

Malik,

Jaglicic

et al. 2024

Inorganica Chimica Acta

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Synthesis, characterization and study of magnetic property of two isomorphic Cu(II) coordination polymers (CP) with chromone based ligand systems

Mandal,

Malik,

Jaglicic

et al. 2024

Inorganica Chimica Acta

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Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

Pavlova,

Pavlov,

Fedin

et al. 2024

Crystal Growth & Design

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Four half-sandwich noble metal complexes containing bis(4-iodopyrazol-1-yl)methane ligand (bpmI), [M(p-cym)-(bpmI)Cl]Cl (M = Ru 2+ and Os 2+ ), and [M(bpmI)(Cp*)Cl]Cl (M = Rh 3+ and Ir 3+ ) were synthesized and characterized by singlecrystal X-ray diffraction analysis. C−I•••Cl halogen bonds between the iodine atoms of the bis(4-iodopyrazol-1-yl)methane and the Cl − anions were found to be the structure-defining contacts for all complexes. Bis(4-iodopyrazol-1-yl)methane acts as both the bidentate ligand and 180°-orienting halogen bond donor in these half-sandwich complexes, which further assemble into halogenbonded polymeric chains. The existence and noncovalent nature of these interactions were confirmed by the topological analysis of the electron density distribution with the help of the atoms in molecules (AIM) approach, followed by noncovalent interactions analysis of the reduced density gradient (RDG). The influence of the nature of the metal center and the presence of solvate molecules on the halogen bond strength was analyzed.

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4,5-Diiodo-1-H-imidazole-derived linker ligand and Cu(i) and Co(ii) coordination polymers based thereupon

Abstract: The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...

Cited by 2 publications

References 82 publications

Synthesis, characterization and study of magnetic property of two isomorphic Cu(II) coordination polymers (CP) with chromone based ligand systems

Synthesis, characterization and study of magnetic property of two isomorphic Cu(II) coordination polymers (CP) with chromone based ligand systems

Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

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