4-Acetamidobenzenesulfonyl azide

Vicarel, Monica; Norris, Peter; Zeller, Mat­thias

doi:10.1107/s1600536806011962

Cited by 4 publications

(4 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Investigation into the behavior of azide group addresses the fundamental search for the difference between azide group and azide ion, which provides valuable evidence for readily forming polymeric nitrogen. However, until now, the high-pressure studies of organic azides are mainly concentrated 17 The structure of 4-ABSA is shown in Figure 1. The hydrogen-bonding interactions allow molecules to pair up and form π-stacked dimers.…”

Section: Introductionmentioning

confidence: 99%

“…Under ambient conditions, 4-acetamidobenzenesulfonyl azide (4-ABSA) belongs to a monoclinic structure with P 2 1 space group and cell parameters of a = 8.0529 Å, b = 22.988 Å, c = 8.3123 Å, and β = 93.534° . The structure of 4-ABSA is shown in Figure .…”

Section: Introductionmentioning

confidence: 99%

“…The structure of 4-ABSA is shown in Figure . The hydrogen-bonding interactions allow molecules to pair up and form π-stacked dimers . The studies of NH 4 N 3 have reported that the hydrogen bonds are affected by the rotation of azide ions with increase in pressure. , The cooperativity of hydrogen bonds and π-stacking interactions allow 4-ABSA to become an attractive candidate for studying the influence of noncovalent interactions within the organic azides in the process of compression.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

High-Pressure Studies of 4-Acetamidobenzenesulfonyl Azide: Combined Raman Scattering, IR Absorption, and Synchrotron X-ray Diffraction Measurements

Jiang

Zhu

et al. 2016

J. Phys. Chem. B

View full text Add to dashboard Cite

We have reported the high-pressure behavior of 4-acetamidobenzenesulfonyl azide (CHNOS, 4-ABSA) by in situ Raman scattering, IR absorption, and synchrotron angle-dispersive X-ray diffraction (ADXRD) measurements in diamond anvil cells with the pressure up to ∼13 GPa at room temperature. All of the fundamental vibrational modes of 4-ABSA at ambient pressure were analyzed by combination of experimental measurements and theoretical calculations using the density functional theory method. Detailed Raman and IR spectroscopic analyses reveal two phase transitions in the pressure region of 0.8-2 and 4.2 GPa, respectively, which are confirmed by the changes in the ADXRD patterns. The first phase transition in the pressure region of 0.8-2 GPa is attributed to the ring distortion and the rotation of CH group, whereas the second phase transition at 4.2 GPa might be induced by the rearrangement of azide group and hydrogen bonds. The analyses of the N vibrational modes suggest that the bent azide group rotates progressively upon compression, which is ascribed to the compression of the unit cell along the b axis. This study is helpful to understand the behavior of azide group and structural evolution of 4-ABSA under high pressure.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

High-Pressure Studies of 4-Acetamidobenzenesulfonyl Azide: Combined Raman Scattering, IR Absorption, and Synchrotron X-ray Diffraction Measurements

Jiang

Zhu

et al. 2016

J. Phys. Chem. B

View full text Add to dashboard Cite

show abstract

“…The azide group is bent, and the N-N-N angle exhibits a typical value of 173.4°. The N3-N4 and N4-N5 bond lengths (1.272(3) and 1.111(3) Å, respectively) are both comparable with those in other sulfonyl azides [24][25][26][27]. In arenesulfonyl azides, the C-S and S-N distances are reportedly sensitive to the electron-withdrawing power of the arene [25].…”

Section: Crystal Structures Of 1 Andmentioning

confidence: 55%

Crystal Structure of 2-Ethylimidazole-1-sulfonyl Azide: A New Azidation Reagent

et al. 2012

View full text Add to dashboard Cite

Abstract:Crystalline 2-ethylimidazole-1-sulfonyl azide was designed as a convenient reagent with improved thermal stability for electrophilic azidation of carbanions. The compound crystallized in the monoclinic space group P2 1 /c. The molecules are arranged into chains by short C-H ... O contacts along a two-fold screw axis. The quaternary 1-azidosulfonyl-2-ethyl-3-methylimidazolium tetrafluoroborate crystallized in Fdd2 with two independent ion pairs which engage in C-H ... F interactions.

show abstract

Synthesis, structure, and reaction of chiral 2-azidoimidazolinium salts: (7aS)-3-azido-5,6,7,7a-tetrahydro-2-[(1R)-1-phenylethyl]-1H-pyrrolo[1,2-c]imidazolium hexafluorophosphate and 2-azido-1,3-bis[(S)-1-phenylethyl]imidazolinium hexafluorophosphate

Kitamura

Ishikawa

Okauchi

2016

Tetrahedron Letters

View full text Add to dashboard Cite

4-Acetamidobenzenesulfonyl azide

Abstract: Key indicatorsSingle-crystal X-ray study T = 100 K Mean (C-C) = 0.003 Å R factor = 0.039 wR factor = 0.099 Data-to-parameter ratio = 16.8For details of how these key indicators were automatically derived from the article, see

Cited by 4 publications

References 5 publications

High-Pressure Studies of 4-Acetamidobenzenesulfonyl Azide: Combined Raman Scattering, IR Absorption, and Synchrotron X-ray Diffraction Measurements

High-Pressure Studies of 4-Acetamidobenzenesulfonyl Azide: Combined Raman Scattering, IR Absorption, and Synchrotron X-ray Diffraction Measurements

Crystal Structure of 2-Ethylimidazole-1-sulfonyl Azide: A New Azidation Reagent

Synthesis, structure, and reaction of chiral 2-azidoimidazolinium salts: (7aS)-3-azido-5,6,7,7a-tetrahydro-2-[(1R)-1-phenylethyl]-1H-pyrrolo[1,2-c]imidazolium hexafluorophosphate and 2-azido-1,3-bis[(S)-1-phenylethyl]imidazolinium hexafluorophosphate

Contact Info

Product

Resources

About