4-Acetylpyridinium perchlorate

Fu, Xue-qun

doi:10.1107/s1600536809024805

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Cited by 3 publications

(2 citation statements)

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“…A search in the CSD 33 of multicomponent solids containing 4-Acpy revealed a total of 5 salts 57–61 and 10 cocrystals. 62–69 Details about the components forming the cocrystals as well as their dimensionalities are provided in the ESI† (Table S1).…”

Section: Resultsmentioning

confidence: 99%

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

et al. 2023

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Section: Resultsmentioning

confidence: 99%

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

et al. 2023

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“…The crystal structures of 4-acetylpyridine together with inorganic acids are also known e.g. with sulfuric acid (Fu, 2009b) and perchloric acid (Fu, 2009a).…”

Section: S1 Commentmentioning

confidence: 99%

Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III)

2010

Acta Cryst E

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Key indicators: single-crystal X-ray study; T = 298 K; mean (C-C) = 0.006 Å; R factor = 0.030; wR factor = 0.070; data-to-parameter ratio = 22.2.The title compound, (C 7 H 8 NO) 6 [Sb 4 Cl 18 ], contains centrosymmetric hexaanions built up from four vertex-sharing alternating SbCl 5 square-based pyramids and highly distorted SbCl 6 octahedra when long (<3.2 Å ) 'secondary' Sb-Cl interactions are taken into account. The inter-polyhedral Sb-Cl bonds define a square-shape. In the crystal, the components are linked by N-HÁ Á ÁCl, C-HÁ Á ÁCl and C-HÁ Á ÁO hydrogen bonds, generating a three-dimensional network. Table 1 Selected bond lengths (Å ). Related literature

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4-Acetylpyridinium iodide

2010

Acta Cryst E

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4-Acetylpyridinium perchlorate

Abstract: In the crystal of the title molecular salt, C7H8NO+·ClO4 −, the ions are linked by N—H⋯O hydrogen bonds, resulting in chains propagating in [010]. The packing is reinforced by C—H⋯O interactions.

Cited by 3 publications

References 1 publication

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III)

4-Acetylpyridinium iodide

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4-Acetylpyridinium perchlorate

Abstract: In the crystal of the title mol­ecular salt, C7H8NO+·ClO4 −, the ions are linked by N—H⋯O hydrogen bonds, resulting in chains propagating in [010]. The packing is reinforced by C—H⋯O inter­actions.

Cited by 3 publications

References 1 publication

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

Virtual assessment achieved two binary cocrystals based on a liquid and a solid pyridine derivative with modulated thermal stabilities

Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III)

4-Acetylpyridinium iodide

Contact Info

Product

Resources

About

Abstract: In the crystal of the title molecular salt, C7H8NO+·ClO4 −, the ions are linked by N—H⋯O hydrogen bonds, resulting in chains propagating in [010]. The packing is reinforced by C—H⋯O interactions.