2009
DOI: 10.1107/s1600536809022569
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4-Hydroxy-3-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl]-2H-chromen-2-one

Abstract: A new chalcone of the coumarin, C21H18O7, containing an annulated α-pyrone ring, was obtained by condensation of the borate complex of ac­yl(hydr­oxy)coumarin with trimethoxy­benzaldehyde. The structure exhibits intra­molecular hydrogen bonding between the hydroxyl oxygen and the ketonic oxygen in the coumarin group. The bicyclic coumarin fragment and the benzene ring form a dihedral angle of 17.1 (4)°. The crystal packing involves dimers inter­connected by C—H⋯O hydrogen bonding.

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Cited by 10 publications
(14 citation statements)
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“…A more accurate description of the structure was presented in [33] but it is important to point out that along the connection between the coumarin Scheme 1. Synthesis of 3-acetyl-4-difluoro boryloxycoumarine.…”
Section: Resultsmentioning
confidence: 99%
“…A more accurate description of the structure was presented in [33] but it is important to point out that along the connection between the coumarin Scheme 1. Synthesis of 3-acetyl-4-difluoro boryloxycoumarine.…”
Section: Resultsmentioning
confidence: 99%
“…In continuation of our previous research [25][26][27] on synthesis and characterization of new asymmetric Schiff base complex, we describe here the synthesis and characterization of the tridentate Schiff base (E)-3-(1-(2-aminoethylimino)ethyl)-4-hydroxy-2H-chromen-2-one (1), then its complexation reaction with cobalt(III) to obtain the complex numbered as (2).…”
Section: Introductionmentioning
confidence: 99%
“…For related structures, see: Traven et al (2000); Sun & Cui (2008); Mechi et al (2009); Hamdi et al (2010); Asad et al (2010). For the synthesis of coumarin chalcones, see: Claisen & Claparede (1881).…”
Section: Related Literaturementioning
confidence: 99%