2002
DOI: 10.1107/s1600536802007237
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(4-tert-Butyl-2-methylthiosemicarbazido)(O-methyldithiophosphato)palladium(II)

Abstract: The title Pd complex, [Pd(C6H14N3S)(CH3O2PS2)], is formed from Pd(acetate)2 and 5‐tert‐butyl­amino‐4‐methyl‐2‐sulfido‐2‐thio­xo‐1,3,4,2λ5‐thia­di­aza­phospho­lan‐5‐onium, (1), in meth­anol. The Pd atom is coordinated to two different ligands which are generated in situ as a result of methano­lysis of the starting compound (1). Thus, Pd is complexed by the O‐methyl­di­thio­phosphate ligand and by 2‐methyl‐4‐tert‐butyl­thio­semicarbazide. Two mol­ecules of the Pd chelate are linked by two intermolecular N—H⋯O hy… Show more

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