1987
DOI: 10.1021/ja00247a021
|View full text |Cite
|
Sign up to set email alerts
|

4-Vinyl-, 6-vinyl-, and 4'-vinyl-2,2':6',2"-terpyridinyl ligands: their synthesis and the electrochemistry of their transition-metal coordination complexes

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

2
106
1
2

Year Published

1998
1998
2009
2009

Publication Types

Select...
6

Relationship

0
6

Authors

Journals

citations
Cited by 185 publications
(111 citation statements)
references
References 2 publications
2
106
1
2
Order By: Relevance
“…The energy process, which indeed is observed in the experimen-compounds 1,2,3,4,5,6,7,8-octahydroacridine-4,5-dione [83] , 2-(2Ј-tal and theoretical studies. The strain in the ligand back-pyridyl)-1,10-phenanthroline (2) [44] , 1,2-dihydrodipyrido[4,3-b;5,6-b]-bone in the terdentate coordinated situations obviously in-acridine (3) [45] , dipyrido[4,3-b;5,6-b]acridine (4) [45] , 4Ј-methylthio-2,2Ј:6Ј,2ЈЈ-terpyridine (5) [46] , Pd(Me)Cl(COD) [72] (COD ϭ 1, 5-creases in the order 6 < 2 < 4, reflecting the tendency of cyclooctadiene), [Pd(Me)(6)]Cl (6a) [32] , [Pd{C(O)Me}(6)]Cl (6d) [32] , the ligand to coordinate in a bidentate fashion. However, and sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (Naligands 6 and 2 can both create space with the same ease BArЈ 4 ) [84] were prepared according to the literature.…”
Section: Comparison Between Theoretical and Experimental Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The energy process, which indeed is observed in the experimen-compounds 1,2,3,4,5,6,7,8-octahydroacridine-4,5-dione [83] , 2-(2Ј-tal and theoretical studies. The strain in the ligand back-pyridyl)-1,10-phenanthroline (2) [44] , 1,2-dihydrodipyrido[4,3-b;5,6-b]-bone in the terdentate coordinated situations obviously in-acridine (3) [45] , dipyrido[4,3-b;5,6-b]acridine (4) [45] , 4Ј-methylthio-2,2Ј:6Ј,2ЈЈ-terpyridine (5) [46] , Pd(Me)Cl(COD) [72] (COD ϭ 1, 5-creases in the order 6 < 2 < 4, reflecting the tendency of cyclooctadiene), [Pd(Me)(6)]Cl (6a) [32] , [Pd{C(O)Me}(6)]Cl (6d) [32] , the ligand to coordinate in a bidentate fashion. However, and sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (Naligands 6 and 2 can both create space with the same ease BArЈ 4 ) [84] were prepared according to the literature.…”
Section: Comparison Between Theoretical and Experimental Resultsmentioning
confidence: 99%
“…expected to be unlikely. We have used the novel rigid ligand 1 and the known ligands 2 [44] , 3 [45] , 4 [45] , 5 [46] , and 6 ( Figure 1). In this series ligands 3 and 4 can be considered as rigid analogs of 5 and tpy (6).…”
Section: Synthesis and Characterization Of Compound 1 And Methylpallamentioning
confidence: 99%
“…Although the preparation of 4Ј-methyl-2,2Ј:6Ј,2"-terpyridine (Mtpy) is well-documented [74] [75] [76] , we have developed a new route which gives high yields (87%) and allows The role of the transition metal is manifold: (i) to gather and orient the system so as to have metallated porphyrins the preparation of large amounts (10 g scale) of this compound. This alternative route to Mtpy involves the reaction held rigidly at a fixed distance and to have asymmetrical systems able to undergo electron-or energy-transfer; (ii) to of 4Ј-trifluoroacetyl-2,2Ј:6Ј,2"-terpyridine [74] [77] with tetramethyltin, using the general procedure described by modulate the electronic coupling between the donor and acceptor porphyrins, and (iii) to form a complex which Stille [78] .…”
Section: Multiporphyrin Linear Systems Assembled By Transition Metal mentioning
confidence: 99%
“…Subsequently, the metal-containing dendrimer 3 was precipitated from the homogeneous solution by the addition of aqueous NH 4 PF 6 solutions. Exhaustive extraction with methanol to remove as a mononuclear metal complex 14) . The appearance of an m.l.c.t.…”
Section: Resultsmentioning
confidence: 99%