2021
DOI: 10.1016/j.gca.2021.08.016
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40Ar/39Ar dating of basaltic rocks and the pitfalls of plagioclase alteration

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Cited by 23 publications
(6 citation statements)
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“…The K/Ca ratio ranges from 0.0009 in the oldest sample (KM1609‐D11‐1 = 117.20 Ma) to 0.0459 in the youngest sample (KM1609‐D3‐12 = 52.19 Ma) with the exception of one sample that has exceptionally high K/Ca ratio of 0.3180 (KM1609‐D10‐9 = 65.01 Ma). This increase in K relative to Ca in the plagioclases (which probably did not originally vary much among samples) likely reflects a progressive addition of K during sericitization (Jiang et al., 2021; Verati & Jourdan, 2013) over tens of millions of years resulting in increasingly lower 40 Ar/ 39 Ar ages. Prolonged fluid flow has been demonstrated by other studies (Fisher & Becker, 2000; Stein & Stein, 1994) and our results further demonstrate the long period over which oceanic crust remains permeable and can undergo alteration.…”
Section: Resultsmentioning
confidence: 94%
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“…The K/Ca ratio ranges from 0.0009 in the oldest sample (KM1609‐D11‐1 = 117.20 Ma) to 0.0459 in the youngest sample (KM1609‐D3‐12 = 52.19 Ma) with the exception of one sample that has exceptionally high K/Ca ratio of 0.3180 (KM1609‐D10‐9 = 65.01 Ma). This increase in K relative to Ca in the plagioclases (which probably did not originally vary much among samples) likely reflects a progressive addition of K during sericitization (Jiang et al., 2021; Verati & Jourdan, 2013) over tens of millions of years resulting in increasingly lower 40 Ar/ 39 Ar ages. Prolonged fluid flow has been demonstrated by other studies (Fisher & Becker, 2000; Stein & Stein, 1994) and our results further demonstrate the long period over which oceanic crust remains permeable and can undergo alteration.…”
Section: Resultsmentioning
confidence: 94%
“…All ages younger than 83.7 Ma (the end of the CNS) are interpreted as an alteration age because EB's oceanic crust was entirely formed during the CNS, and all samples that are younger than this age cutoff also show signs of alteration or discordance in their degassing patterns. This includes disturbed age spectra that may or may not yield an age plateau due to alteration or 39 Ar or 37 Ca recoil (Schaen et al., 2021) or variable K/Ca patterns and age spectra in plagioclase analyses likely due to partial sericitization (Jiang et al., 2021; Verati & Jourdan, 2013). Some plagioclase samples appear to yield reliable age spectra with age plateaus containing more than 50% of the released 39 Ar (K) (e.g., KM1609‐D10‐09 or D07‐01) but are too young for the region as mentioned above (Figures 4c and 4d), or have ages conflicting with other samples collected at the same dredge location (e.g., KM1609‐D7; Table 1).…”
Section: Resultsmentioning
confidence: 99%
“…6), consisting of 42% of 39 Ar released, followed by an extended high temperature/excess Ar recoil pattern. The remaining plagioclase separates (n = 7) were marred by multiple excess Ar domains, coupled with low-degree sericitization that resulted in discordant age spectrums (e.g., Jiang et al, 2021). In total, three samples produced age determinations with plateau ages containing at least 40% of the 39 Ar argon released (Table 1).…”
Section: Ar/ 39 Ar Geochronologymentioning
confidence: 99%
“…However, K-Ar and Rb-Sr systematics can easily be modified by alteration 15 , with previous workers recognising that the K contents of dated phlogopite in the main diatreme complex were "anomalously low" and indicative of partial chloritization 12 . The extensive alteration of K-bearing minerals means they are likely unsuitable as geochronometers for Argyle 16 . Although there is relatively fresh phlogopite in some of the lamproite dykes 17 , dating it with high-precision 40 Ar/ 39 Ar has proved challenging due to the presence of excess radiogenic Ar.…”
mentioning
confidence: 99%