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Cited by 11 publications
(9 citation statements)
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References 6 publications
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“…It has been shown for cyclohexane as well that a direct ring opening of six-membered hydrocarbon rings is unfavorable and the isomerization to methylcyclopentane is needed to facilitate the ring opening to acyclic hydrocarbons [4]. This agrees with the observations of the present study.…”
Section: Skeletal Isomerization Of Decalinsupporting
confidence: 93%
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“…It has been shown for cyclohexane as well that a direct ring opening of six-membered hydrocarbon rings is unfavorable and the isomerization to methylcyclopentane is needed to facilitate the ring opening to acyclic hydrocarbons [4]. This agrees with the observations of the present study.…”
Section: Skeletal Isomerization Of Decalinsupporting
confidence: 93%
“…Since isomers are formed almost exclusively at the beginning of the reaction, it can be assumed that the protolytic dehydrogenation (1) is the prevailing initiation step. Either of the formed carbenium ions can undergo skeletal isomerization, which proceeds via the cornerprotonated cyclopropane ring (3) [11], or hydride transfer from decalin to the adsorbed carbenium ion resulting in formation of decalin carbenium ions and desorption of the saturated product (4). Furthermore, the dinaphthene carbenium ion can undergo β-scission leading to an alkenylnaphtene carbenium ion (6).…”
Section: Ring Opening Of Decalin and Isomersmentioning
confidence: 99%
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“…During the hydroisomerization of model hydrocar bons in a flow system [1,[18][19][20][21][22][23], most catalysts exhibit the selectivity for desired products higher than 95%, usually, in the range of low and medium conver sion values (less than 40 wt %). In this study, to esti mate the properties of the hydroisomerization cata lysts, we selected the reactant hydrocarbon conversion at which the selectivity is at least 90%.…”
Section: Resultsmentioning
confidence: 99%
“…Cyclohexane (and decaline) opening catalysts based on metal-oxide and metal-zeolite systems were studied earlier at 200-500°C and 0.1-5.0 MPa [44,45]. It was established that not only the nature of the metal (Rh, Pt, Pd, Ir, or Ru) but also the properties of the support (Al 2 O 3 , Al 2 O 3 -F, La 2 O 3 -ZrO 2 , SiO 2 , etc.)…”
Section: Cyclohexanesmentioning
confidence: 99%