426. The preparation of a stable aluminium dodecanoate (laurate) with no gelling properties in hydrocarbons

Glazer, J.; McRoberts, T. S.; Schulman, J. H.

doi:10.1039/jr9500002082

Cited by 10 publications

(2 citation statements)

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“…In many cases, soap hydrates as well as basic [M(OH) x (RO 2 )], and or acidic [(RCO 2 ) n M(RO 2 H)], compounds were obtained. For example, studies involving the synthesis of aluminium(III) carboxylates resulted in the formation of both acidic and basic products [43][44][45]. After many attempts to produce the anhydrous tri-soap, it was demonstrated that it could be prepared only under anhydrous conditions [20,46,47].…”

Section: Approach To Synthesismentioning

confidence: 99%

Theories and experimental investigations of the structural and thermotropic mesomorphic phase behaviors of metal carboxylates

Nelson

Taylor

2014

Appl Petrochem Res

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Investigations on the phase behaviors and structural properties of mono-, di-and poly-valent metal carboxylates are reviewed with reference to developments in experimental and theoretical concepts surrounding their liquid crystalline properties. The main methods of structural investigation such as X-ray diffraction, infrared and 13 C-NMR spectroscopies are examined in detail on the basis of common synthetic routes leading to the isolation of pure compounds. A detailed review of the thermal behaviors of several metal carboxylates is presented along with proposed theories and molecular models for odd-even alternation, chain length effects, phase structures and mesophase formation. Theories explaining the effects of metal ion radii and chain unsaturation are also discussed. Proposed degradation mechanisms resulting in the formation of various products and kinetic studies are also considered. Though this review highlights a number of investigations on the structural and phase properties of the mostly widely studied carboxylates, the results presented here strongly indicate that there is room for further studies on some of these systems.

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Section: Approach To Synthesismentioning

confidence: 99%

Theories and experimental investigations of the structural and thermotropic mesomorphic phase behaviors of metal carboxylates

Nelson

Taylor

2014

Appl Petrochem Res

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“…Originally it was claimed that they could be produced by aqueous metathesis, but this now seems unlikely (2). Aluminum tridodecanoate can be prepared (27) by treating trimethylaluminum with pure dodecanoic acid in dry benzene, and trituration with dry, light petroleum ether. The product is a yellow amorphous powder, m.p.…”

Section: Preparation Of Heavy Metal Soaps a Soaps Based On Carboxylic...mentioning

confidence: 99%

Properties of Organic Solutions of Heavy Metal Soaps.

Pilpel¹

1963

Chem. Rev.

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The preparation of aluminium soaps by a continuous process. I. Aluminium laurate

Woods¹,

Taylor²

1958

J. Appl. Chem.

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An account is given of the laboratory preparation of aluminium dilaurate using a continuous process. The effect, on the quality of the soap produced, of changing variables such as concentration and proportions of the reacting solutions, degree of agitation and time and temperature of reaction, has been found. It is shown that the product of the best quality, when judged by the consistency and storage stability of gels in hydrocarbons, is obtained when the reaction pH is kept within the range 3.5–4.0. The process was later successfully transferred to a pilot plant.

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426. The preparation of a stable aluminium dodecanoate (laurate) with no gelling properties in hydrocarbons

Cited by 10 publications

References 0 publications

Theories and experimental investigations of the structural and thermotropic mesomorphic phase behaviors of metal carboxylates

Theories and experimental investigations of the structural and thermotropic mesomorphic phase behaviors of metal carboxylates

Properties of Organic Solutions of Heavy Metal Soaps.

The preparation of aluminium soaps by a continuous process. I. Aluminium laurate

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