Gromov asked if the bi-invariant metrics on a compact Lie group are extremal compared to any other metrics. In this note, we prove that the bi-invariant metrics on a compact connected semi-simple Lie group G are extremal (in fact rigid) in the sense of Gromov when compared to the left-invariant metrics. In fact the same result holds for a compact connected homogeneous manifold G/H with G compact connect and semi-simple.