Org. Biomol. Chem.
 2024
DOI: 10.1039/d3ob01895d
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5-exo-Selective asymmetric bromolactonization of stilbenecarboxylic acids catalyzed by phenol-bearing chiral thiourea

Masayuki Sugano,
Tsubasa Inokuma,
Yousuke Yamaoka
et al.

Abstract: We developed a novel thiourea Lewis-base catalyst with phenol moieties for the enantioselective 5-exo-bromolactonization of stilbenecarboxylic acids to afford chiral 3-substituted phthalides.

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