2010
DOI: 10.1107/s160053681000468x
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{5-Methoxy-2-[(2-morpholinoethyl)iminomethyl]phenolato}(thiocyanato-κN)nickel(II)

Abstract: Key indicators: single-crystal X-ray study; T = 298 K; mean (C-C) = 0.004 Å; R factor = 0.036; wR factor = 0.090; data-to-parameter ratio = 17.0.In the mononuclear title complex, [Ni(C 14 H 19 N 2 O 3 )(NCS)], the nickel(II) atom is four-coordinated in a square-planar geometry by the O and N atoms of the tridentate Schiff base ligand and by the N atom of a thiocyanate ligand. The crystal structure is stabilized by intermolecular C-HÁ Á ÁS and C-HÁ Á ÁO hydrogen bonds, forming a three-dimensional network. Rel… Show more

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