55. Mechanism of substitution at a saturated carbon atom. Part IV. A discussion of constitutional and solvent effects on the mechanism, kinetics, velocity, and orientation of substitution

Studies of Solvent Effect of Aquo-Methanol Solvent System on Kinetics and Activation Parameters of Base Catalised Hydrolysis of Ethyl Cinnamate

“…From Table 1 it is observed that the values of specific rate constant is decrease with increase of temperature which is quite in agreement with theory of Hughes and Ingold [4] and Singh et al [5].…”

Studies of Solvent Effect of Aquo-Methanol Solvent System on Kinetics and Activation Parameters of Base Catalised Hydrolysis of Ethyl Cinnamate

“…From Tab-1 it is observed that the values of specific rate constant is decrease with increase of temperature which is quite in agreement with theory of Hughes and Ingold [4] and Singh A K [5] …”

Kinetics and Solvent Effect in Hydrolysis of Ethyl Cinnamate in Water- Methanol Mixture

“…The above noted two depleting factors are quite in operation and are with good agreement with theory of Hughes and Ingold [4] that rate ought to decrease with decreasing dielectric constant of the reaction media. Such decrease in rate constant with increasing proportion of organic co-solvent like methanol have also reported by Elsemongy [5], and recently by Singh [6].…”