“…Due to the semimetal/narrow bandgaps of bulk mercury chalcogenides and their concomitant large Bohr exciton radii (∼40 nm), Hg X ( X = S, Se, Te) nanocrystals display extreme bandgap tunability, from 1.5 eV to 20 meV (830 nm to 6.2 μm) for HgTe. − For this reason, Hg X QDs are explored as low-cost solution processable alternatives for midwave infrared (3–5 μm) photodetection. , However, using HgTe QDs to explore short wave infrared (1 to 2 μm) imaging remains unexplored. There is great commercial interest in short wave infrared (SWIR) imaging due to the high spatiotemporal resolution for applications such as defense, noninvasive biomedical imaging, mobile devices, machine vision, advanced drive-assistance programs in cars, and more. − To date, most mercury chalcogenide QD research has focused on larger particles with optical bandgaps beyond the current detection range of commercial SWIR cameras (greater than 1600 nm). − Considerably less is known about the synthetic routes and optical properties of small (<3 nm) HgTe QDs, despite potential applications in near and shortwave infrared (NIR/SWIR) technologies such as SWIR imaging agents, photodetectors, light-emitting diodes, and other optoelectronic applications. − ,− …”