8.28 Reduction of SulfurCarbon Bonds and of Other Heteroatoms Bonded to Tetrahedral Carbon

Manthorpe, Jeffrey M.; Kong, Han Il; Palko, J.W.; Gill, Monica A.

doi:10.1016/b978-0-08-097742-3.00830-2

Comprehensive Organic Synthesis II 2014

DOI: 10.1016/b978-0-08-097742-3.00830-2

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8.28 Reduction of SulfurCarbon Bonds and of Other Heteroatoms Bonded to Tetrahedral Carbon

Jeffrey M. Manthorpe

Han Il Kong

J.W. Palko

et al.

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2015

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“…To evaluate the generality of the Cr–ligand–Mn-mediated reduction system, we investigated various α-sulfur-substituted ketones . Reductive cleavage of α-(phenylthio), α-(phenylsulfinyl), and α-(phenylsulfonyl) groups ( 9a – c ) proceeded smoothly in the Cr–ligand–Mn system to give corresponding cyclohexanone 10 in good yield (Table ).…”

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confidence: 99%

Novel and Efficient Chromium(II)-Mediated Desulfonylation of α-Sulfonyl Ketone

et al. 2015

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A novel and efficient method for the Cr(II)-mediated desulfonylation of α-sulfonyl ketone by a Cr-ligand-Mn system has been developed during the course of process research on Halaven (eribulin mesylate). This reaction is dramatically accelerated in the presence of an appropriate bipyridyl-type ligand. This system is applicable to reduction of α-sulfur-substituted ketones. In addition, a Cr-Cp2ZrCl2-Mn catalytic system is also applicable to desulfonylation of α-sulfonyl ketone.

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confidence: 99%

Novel and Efficient Chromium(II)-Mediated Desulfonylation of α-Sulfonyl Ketone

et al. 2015

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8.28 Reduction of SulfurCarbon Bonds and of Other Heteroatoms Bonded to Tetrahedral Carbon

Cited by 1 publication

References 703 publications

Novel and Efficient Chromium(II)-Mediated Desulfonylation of α-Sulfonyl Ketone

Novel and Efficient Chromium(II)-Mediated Desulfonylation of α-Sulfonyl Ketone

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