848. The infrared spectra of cobalt(III) ethylenediamine complexes. Part I. Vibrations of the ethylenediamine chelate ring

Baldwin, M. E.

doi:10.1039/jr9600004369

Cited by 101 publications

(19 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The corresponding bands in the N-deuterated complexes appeared a t about 1 180-1 170 cm-l, in agreement with published data for other ethylenediamine metal complexes (6,7).…”

supporting

confidence: 79%

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Allen¹,

Senoff²

1965

Can. J. Chem.

View full text Add to dashboard Cite

A number of complexes [Ru(en),]S?, where X = I-, Br-, P~C I A~-, CIOA-, and PFe-, have been prepared and their infrared spectra measured in the solid state between 4 000-600 cm-l. The effect of the various anions on the spectra and assignments for the observed fundamental vibrations are discussed.The infrared spectra of ethylenediamine complexes have recently been reviewed (I). The available infrared data suggest that ethylenediamine coordinates to a metal with the gauche configuration (2). This has been substantiated by X-ray structural data for a number of ethylenediamine colnplexes (3, 4, 5). In this paper we report the preparation of a series of ruthenium(I1) complexes, [ R~( e n )~l X ? , where en = ethylenediamine and X = I-, Br-, PtClt-, C1O4-, and P F c . The infrared data for these coinplexes are given in Table I. Data for the N-deuterated con~plexes are found in Tables I1 and 111.

show abstract

“…The corresponding bands in the N-deuterated complexes appeared a t about 1 180-1 170 cm-l, in agreement with published data for other ethylenediamine metal complexes (6,7).…”

supporting

confidence: 79%

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Allen¹,

Senoff²

1965

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

“…For the assignment of geometrical configuration to these complexes, infrared spectroscopy was used. Various workers have employed [31][32][33][34][35][36] the NH 2 deformation mode in the 1700-1500 cm )1 region, CH 2 rocking mode in the 900-850 cm )1 and M-N stretching mode in the 610-500 cm )1 region to distinguish between the cis-and trans-isomers of chromium(III)-ethylenediamine complexes. Baldwin [34] suggested that the most consistent variations between the spectra of cisand trans-isomers were found in the CH 2 rocking region (900-850 cm )1 ).…”

Section: Spectroscopic Characterizationmentioning

confidence: 99%

“…Several attempts have been made to relate differences in the infrared spectra to the geometrical configuration structure of the complexes [31][32][33][34][35][36]. For the assignment of geometrical configuration to these complexes, infrared spectroscopy was used.…”

Section: Spectroscopic Characterizationmentioning

confidence: 99%

Metallosurfactants of Chromium(III) Coordination Complexes. Synthesis, Characterization and Determination of CMC Values

Kumaraguru

Arunachalam

Arumugham

et al. 2006

Transition Met Chem

View full text Add to dashboard Cite

A number of mixed ligand chromium(III)-surfactant coordination complexes, of the type cis-[Cr(en) 2 (A)X] 2+ and cis-a-[Cr(trien)(A)X] 2+ (A = Dodecyl or Cetylamine; X = F ) , Cl ) , Br ) ) were synthesized from the corresponding dihalogeno complexes by ligand substitution. These compounds form foam in aqueous solution when shaken. The critical micelle concentration (CMC) values of these surfactant metal complexes in aqueous solution were obtained from conductance measurements. Specific conductivity data (at 303, 308 and 313 K) served for evaluation of the temperature-dependent critical micelle concentration (cmc) and the thermodynamics of micellization (DG 0 m , DH 0 m and DS 0 m ).

show abstract

“…absorption bands of the two compounds together with tentative assignnients of the various bands are given in Table 3. Given that both compounds A and C are cyanoamminebis(ethylenediamine)cobalt(III) salts, a comparison of the spectra of the two compounds in the 1580-1620, 870-900 and 610-500 cm-' regions would lead to the prediction that compound A had the cis-configuration and compound C had the trans-configuration (15)(16)(17).…”

Section: T L~t R L L~~l E~~i~mentioning

confidence: 99%

Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen₂NH₃NCS]²⁺: The Preparation and Properties of trans-[Coen₂NH₃CN]²⁺

Norris¹,

Wilson²

1973

Can. J. Chem.

View full text Add to dashboard Cite

The hydrogen peroxide oxidation of thiocyanate ion in cis-and trntls-[Coen2NH3NCSI2+ leads to the formation of the corresponding cis-and tratls-cyanoanimine-and diamminebis(ethylenediamine)cobalt-(111) complexes. The spectral properties of the previously unreported t r n t~s -[ C o e n~N H~C N ]~+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trotn-[Coen2NH3NCS]" to trntrs-[Coen2NH3CNI2+.L'oxydation par le peroxyde d'hydrogene de I'ion thiocyanate dans le [CoenlNH3NCSI2 +-cis et -tratn conduit a la formation des con~plexes ciset tt.ntiscyanoamine et diamine bis(Cthy1enediarnine) cobalt (Ill). Les proprittes spectrales du conlpose, pas encore decrit, [Coen2NH3CNI2+-trnns sont rapporttes et comparees a celles de I'isoniere-ci.7.On fait certaines observations concernant les conditions de reaction clui favorisent une conversion co~npltte du [ C~e n~N H~N C S ]~+ -t r a t w en [Cocn2NH3CNI2+-trotrs.

show abstract

848. The infrared spectra of cobalt(III) ethylenediamine complexes. Part I. Vibrations of the ethylenediamine chelate ring

Abstract: Baldwin. 4369 848. The Infrared 8pectra of Cobalt(Ir1) Ethylenediarnine Complexes. Part I . Vibrations of the Ethylenediamine Chelate Ring.

Cited by 101 publications

References 0 publications

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Metallosurfactants of Chromium(III) Coordination Complexes. Synthesis, Characterization and Determination of CMC Values

Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen₂NH₃NCS]²⁺: The Preparation and Properties of trans-[Coen₂NH₃CN]²⁺

Contact Info

Product

Resources

About

848. The infrared spectra of cobalt(III) ethylenediamine complexes. Part I. Vibrations of the ethylenediamine chelate ring

Abstract: Baldwin. 4369 848. The Infrared 8pectra of Cobalt(Ir1) Ethylenediarnine Complexes. Part I . Vibrations of the Ethylenediamine Chelate Ring.

Cited by 101 publications

References 0 publications

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Infrared Spectra of Tris-Ethylenediamine Complexes of Ruthenium (Ii)

Metallosurfactants of Chromium(III) Coordination Complexes. Synthesis, Characterization and Determination of CMC Values

Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen2NH3NCS]2+: The Preparation and Properties of trans-[Coen2NH3CN]2+

Contact Info

Product

Resources

About

Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen₂NH₃NCS]²⁺: The Preparation and Properties of trans-[Coen₂NH₃CN]²⁺