935. Oxides and oxy-ions of the non-metals. Part III. Oxy-radicals of chlorine

Abstract

Hyperfine and g-tensors for chlorine monoxide, dioxide, and trioxide areThe identity of radicals trapped in y-irradiated perchlorates presented. and chlorates and detected by electron-spin resonance is discussed.

Magnetic resonance studies of metal–olefin complexes. I. Electron spin resonance spectra of γ-irradiated silver perchlorate cycloalkene complexes

“…The available spectral parameters of Ago, Ag' ' (17), and the chlorine oxyradicals (18,19) eliminate them as possible species responsible for the observed spectra. Since cycloolefins and some of their adducts yield cycloalkenyl radicals when subjected to ionizing radiation (20,21), it is probable that the corresponding Ag'cycloalkenyl radicals are produced upon y-irradiation of the silver~ycloalkene complexes (eq.…”

ELECTRON SPIN RESONANCE SPECTRA OF S2O2− IN IRRADIATED THIOSULFATE SINGLE CRYSTALS

“…Tetrahedral radicals such as SO4-and P042-have been detected (19), and the principal g-values for SO4-h persulfate are 2.033,2.008,2.004 (average 2.0149). Such radicals are expected to possess a .…”

Electron Spin Resonacnce of γ‐Defects in Ferroelectric Ammonium Hydrogen Sulfate

“…As may be seen, two groups of lines appear: sample in the resonant cavity. It can be attributed to ionic SO-defects established to appear in irradiated potassium persulfate (8).…”