The 67 Zn(n,p) 67 Cu, 64 Zn(n,2n) 63 Zn, 89 Y(n,γ) 90m Y and 89 Y(n,2n) 88 Y reaction cross sections relative to the 197 Au(n,2n) 196 Au monitor reaction have been determined at the neutron energy of 14.54 ± 0.002 MeV by using the method of activation and off-line γ-ray spectrometry. The neutron energy used was obtained from the 3 H(d,n) 4 He reaction. The covariance analysis was performed by taking the uncertainties arising in various attributes and the correlations between those attributes. The analyzed results from the present measurement were compared with the literature data and evaluated data of various libraries like ENDF/B-VIII, JEFF-3.3, JENDL-4.0 and ROSFOND-2010 libraries as well as with the calculated values based on TALYS-1.9 code. Keywords 67 Zn(n,p) 67 Cu • 64 Zn(n,2n) 63 Zn, 89 Y(n,γ) 90m Y and 89 Y(n,2n) 88 Y reactions • 3 H(d,n) 4 He reaction neutron • γ-Ray spectrometry • Covariance analysis • TALYS-1.9