The context, which allowed to write this article is the fact that we have noticed an increase in the environmental impact caused by the poor management of car parks and fuel sellers as well as the proliferation of service stations that do not respect any standards. The illegal storage and marketing of petroleum products, especially gasoline, in the city of N'Djamena is the main factor of vulnerability and criticality of air pollutants, thus demonstrating the growing environmental impact in the city of N'Djamena. The presence of Polycyclic Aromatic Hydrocarbons (PAHs) as well as that of fine particles which are part of the Persistent Organic Pollutants (POPs) and characterize by their toxicities, their persistence in the environment, their bioaccumulation in living tissues, and their long-distance transport. Thus, the main objective of this work is to determine and evaluate the physical properties of gasoline and the presence of fine particles in the ten districts of the city of N'Djamena. These are the species sold on the street and presenting a danger to users. The main idea would be to look for gas stations and points of sale that comply with the regulations in force and those that do not. Then physical analyses were carried out on different types of gasoline consumed and then the air quality was measured with a Purple Air sensor. In conclusion, a complete structure of the ten districts with their degrees of pollution as well as the number of gas stations and fuel sellers on the street will be listed.