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Fukuzawa, Takao

doi:10.1295/kobunshi.28.710

Kobunshi

1979

DOI: 10.1295/kobunshi.28.710

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Takao Fukuzawa¹

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1997

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“…(3) and (4) with the state parameters were about 35 (mN/m). As the y values of P2EHA are larger than that of P(VDF-HFA), we judged that the Downloaded by [University of Western Ontario] at 09:Relationship between specific volume, and temperature for PZEHA-H.…”

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Segregation Behavior Found in Poly(2-ethylhexyl acrylate)/Poly-(vinylidenefluoride-co-hexafluoro acetone) Blends

Kano

Katayama

Akiyama

et al. 1997

The Journal of Adhesion

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The surface and bottom compositions of poly(2-ethylhexyl acrylate) (PZEHA)/poly-(vinylidene fluoride-co-hexafluoro acetone) [P( VDF-HFA)] blends were investigated by XPS analysis. In these blends, the enriched P(VDF-HFA) layer was observed from the top surface to a few nm depth, while the PZEHA component segregated at the bottom (the surface in contact with release liner). The probe tack values of the bottom side were remarkably larger than those of the surface side for the PZEHA/P(VDF-HFA) blends because the characteristic segregation structure was formed. We expected that the PZEHA/P(VDF-HFA) blends could be utilized as a non-backing pressure sensitive adhesive (PSA) tape. The effects of the film thickness of the blends and the molecular weights of P2EHA on the segregation structure were also examined. We thought that segregation behavior found in P2EHA/P(VDF-HFA) blends was caused by several factors, such as surface tension, miscibility, density, and rate of solvent casting.

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confidence: 99%

Segregation Behavior Found in Poly(2-ethylhexyl acrylate)/Poly-(vinylidenefluoride-co-hexafluoro acetone) Blends

Kano

Katayama

Akiyama

et al. 1997

The Journal of Adhesion

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Cited by 1 publication

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Segregation Behavior Found in Poly(2-ethylhexyl acrylate)/Poly-(vinylidenefluoride-co-hexafluoro acetone) Blends

Segregation Behavior Found in Poly(2-ethylhexyl acrylate)/Poly-(vinylidenefluoride-co-hexafluoro acetone) Blends

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