“…Therefore, the principal purpose of our study is to identify the crystal structures of copper(II)-HPPK complexes in combination with different anions exhibiting flexible binding modes and to examine their thermal properties. Having fully characterized the compounds, our intention was to investigate the application of these complexes as precursors in spin coating processes (SC), which is an efficient method to grow polymeric (Hall et al, 1998), inorganic (Partridge et al, 1996;Sathaye et al, 2003), and metallic (Kim et al, 2008) thin films with easily controlled coating coverage (Schubert & Dunkel, 2003). Moreover, the technique can also be employed to deposit layers of transition metal complexes with interesting magnetic, optical, or catalytic properties (Bräuer et al, 2006;Elschner et al, 2001).…”