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Cited by 4 publications
(5 citation statements)
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“…4 data using this model were 2J 1 = 151 cm -1 and 2J 2 = -220 cm -1 . The intramolecular FM interaction J 1 is in the range observed in similar systems [28,[30][31][32][33][34][35]. Since no increase of χT occurred as temperature decreases, multiple fits were attempted while assuming both J 1 and J 2 to be AFM;…”
Section: Resultsmentioning
confidence: 99%
“…4 data using this model were 2J 1 = 151 cm -1 and 2J 2 = -220 cm -1 . The intramolecular FM interaction J 1 is in the range observed in similar systems [28,[30][31][32][33][34][35]. Since no increase of χT occurred as temperature decreases, multiple fits were attempted while assuming both J 1 and J 2 to be AFM;…”
Section: Resultsmentioning
confidence: 99%
“…Similar stuctures are exhibited by bis(hexafluoropentadionato) copper complexes of imidazole (Colacio et al, 2000), pyrazole (Kogane et al, 1990;Fokin et al, 2002) and substituted pyridines (De Panthou et al, 1996;Iwahori et al, 2001;Sano et al, 1997).…”
Section: Related Literaturementioning
confidence: 68%
“…The χ T decreases monotonically upon lowering the temperature, which suggests the presence of strong antiferromagnetic exchange interactions (Figure ). Previous studies have established a ferromagnetic character of intramolecular exchange interactions in M-NC–N-•O fragments for imino-coordinated complexes, ,,, and a few of them exhibit strong antiferromagnetic intermolecular exchange interactions due to the effective overlap of magnetic orbitals of NO groups. ,, We assumed that the magnetic behavior of 1 can arise from the short O NO ···O NO distance and θ angle close to 90° in mutual arrangement of the neighboring A molecules (Table , Figure a).…”
Section: Results and Discussionmentioning
confidence: 98%
“…Taking into account paramagnetic species presented in the compound 2, this EPR signal was attributed to free nitroxide defects. 24,29,31 When temperature of the 2 sample goes below the transition point, broad intense lines appear in EPR spectra (Figures 5 and S3−S5).…”
Section: ■ Results and Discussionmentioning
confidence: 99%
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