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Leonov, O. N.; Shcherbakov, V. M.; Kryukova, L. Yu.; Vorontsov, E. A.; Kuznetsov, S. L.; Kryukov, L. N.

doi:10.1023/a:1011385405611

Cited by 3 publications

(3 citation statements)

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“…The alcohols 5 and 6 were synthesized as per the published procedure. , The alcohols 7 and 8 were synthesized as per the modified, published procedure (Scheme S1). , The synthetic procedure and the relevant structural analysis are described below.…”

Section: Methodsmentioning

confidence: 99%

“…The alcohol 8 was prepared by a modified literature procedure . Propionic acid (3.7 g, 50 mmol) was dissolved in 50 mL of DCM.…”

Section: Methodsmentioning

confidence: 99%

“…The alcohol 8 was prepared by a modified literature procedure. 24 Propionic acid (3.7 g, 50 mmol) was dissolved in 50 mL of DCM. At 0 °C, triethylamine (2 equiv, 13.9 mL, 100 mmol) was added and methyl chloroformate (2 equiv, 9.45 g, 100 mmol) was slowly added.…”

Section: ■ Experimental Sectionmentioning

confidence: 99%

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Theoretical and Experimental Study of Monofunctional Vinyl Cyclopropanes Bearing Hydrogen Bond Enabling Side Chains

et al. 2021

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The synthesis of four different monofunctional vinyl cyclopropane (VCP) derivatives and their polymerization behavior is presented. The different VCPs have different capabilities to form hydrogen bonds in their side chain. A preorganization due to these hydrogen bonds should lead to a fast polymerization. Kinetic studies, hydrogen-bond strength, and theoretical calculations were used to correlate the degree of conversion and the amount of preorganization. While VCPs capable of hydrogen bonding did not show a huge difference, a general effect of hydrogen bonds on polymerization behavior could be observed.

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