1999
DOI: 10.1023/a:1008992228421
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Cited by 15 publications
(18 citation statements)
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“…Nawrocki [24] and Jaroniec [25] have explainedt he relationship between isotherm shape and pore structure and size distribution. In brief, ap orous adsorbent having at ype IV isotherm with an H1 hysteresis loop is most favorable for adsorption purposes.T his type is associated with capillaryc ondensation taking place in mesopores andi sc haracteristico famaterial composed of agglomerates of approximately uniform spheres in af airly regular array with an arrow distribution of pore sizes.…”
Section: Pore Naturementioning
confidence: 99%
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“…Nawrocki [24] and Jaroniec [25] have explainedt he relationship between isotherm shape and pore structure and size distribution. In brief, ap orous adsorbent having at ype IV isotherm with an H1 hysteresis loop is most favorable for adsorption purposes.T his type is associated with capillaryc ondensation taking place in mesopores andi sc haracteristico famaterial composed of agglomerates of approximately uniform spheres in af airly regular array with an arrow distribution of pore sizes.…”
Section: Pore Naturementioning
confidence: 99%
“…The phenomenon that the adsorption features of the original MARs in Figure 4d id not show ac lear capillarye ffect indicated that the isotherm of the originalM ARs was at ype IV isotherm with ah ysteresis loop intermediate between H2 and H3. [24][25] This type of hysteresis loop suggested that the pores wereo f an "ink bottle" shape, [26] which offers inefficient adsorption due to the slow diffusion of solute and solventm olecules in and out of these pores.W orkb yt he group of Da confirmed this phenomenon. [27] Furthermore, for conventionalp reparation techniques, there is ac ontradictionb etween high surface area and appropriate pore structure.…”
Section: Pore Naturementioning
confidence: 99%
“…(4) can be rewritten in the well-known, Jaroniec-type linear relationship form [17]: (4) can be rewritten in the well-known, Jaroniec-type linear relationship form [17]:…”
Section: Theorymentioning
confidence: 99%
“…The results are compared with those obtained from the Jaroniec equation [17]. The results are compared with those obtained from the Jaroniec equation [17].…”
Section: Introductionmentioning
confidence: 96%
“…In several research directions, there is a critical need for ordered super-microporous silicas with narrow size distribution. In the pore size range of 1.0-2.0 nm, the determination of pore size by gas adsorption is still an open issue for lack of standard samples of well-defined pore sizes [13]. Secondly, in the investigation of the confinement effects on chemical reactions, the size near 1.5 nm is an important one to show critical size effect.…”
Section: Introductionmentioning
confidence: 99%